The microstructure and morphology of solid-oxide fuel-cell electrodes are very complex but important because they strongly affect the electrical performance of the cell. In this work the high-resolution X-ray nanotomography technique is applied to reconstruct the three-dimensional microstructure of a (La(0.8)Sr(0.2))(0.95)MnO(3) yttria-stabilized zirconia composite cathode. Some key microstruct...

Diierent bounds on the conductivity of a composite material may improve on each other in diierent conductivity regimes. If so, the question arises of how to eeciently interpolate between the bounds. In this paper we show how to do an interpolation with a two-point Pad e approximation method. For bounds on two-component composites the interpolation method is shown to be, in a sense, the best pos...

Porous yttria-stabilised zirconia ceramics have been gaining popularity throughout the years in various fields, such as energy, environment, medicine, etc. Although yttria-stabilised zirconia is a well-studied material, voided yttria-stabilised zirconia powder particles have not been demonstrated yet, and might play an important role in future technology developments. A sol-gel synthesis accomp...

Crystal structure and compressibility of potassium azide was investigated by in-situ synchrotron powder X-ray diffraction in a diamond anvil cell at room temperature up to 37.7 GPa. In the bodycentered tetragonal (bct) phase, an anisotropic compressibility was observed with greater compressibility in the direction perpendicular to the plane containing N3 ions than directions within that plane. ...

objectives: masking ability of a restorative material plays a role in hiding colored substructures; however, the masking ability of zirconia ceramic (zrc) has not yet been clearly understood in zirconia-based restorations. this study evaluated the effect of three different core materials on masking ability of a zrc. materials and methods: ten zirconia disc samples, 0.5mm in thickness and 10mm i...

objectives : studies on the effect of coloring procedures on the bond strength of zirconia to resin cement are lacking in the literature. this study evaluated the effect of dipping of zirconia ceramic in different liquid color shades on the microtensile bond strength (mtbs) of zirconia ceramic to resin cement. materials and methods: this in vitro study was conducted on 100 microbar specimens di...

Degradation of yttria-stabilized zirconia dental implants abutments due to the tetragonal to monoclinic phase transformation was studied in detail by microstructural characterization using Electron Back Scatter Diffraction (EBSD). The amount and distribution of the monoclinic phase, the grain-size distribution and crystallographic orientations between tetragonal and monoclinic crystals in 3 mol...

Problem statement: This study presented bone like apatite formation on yttria stabilized zirconia in Simulated Body Fluid (SBF) through hydroxylation technique. Approach: Sol gel route was used to prepare yttria stabilized zirconia. Then it was hydroxylated with 5M H3PO4 for formation of Zr-OH group. Moreover, the growth rate of calcium and phosphate on zirconia substrate was examined using sim...

Metal sulfate formation is one of the major challenges to the emission aftertreatment catalysts. Unlike the incredibly sulfation prone nature of Pd to form PdSO4, no experimental evidence exists for PtSO4 formation. Given the mystery of nonexistence of PtSO4, we explore PtSO4 using a combined approach of an evolutionary algorithm based search technique and quantum mechanical computations. Exper...

In this work, we propose a method to improve electro-optical and structural parameters of light-absorbing kesterite materials. It relies on the application of weak power hydrogen plasma discharges using electromagnetic field of radio frequency range, which improves homogeneity of the samples. The method allows to reduce strain of light absorbers and is suitable for designing solar cells based o...