supported catalysts synthesized via the interaction of mg(oet)2 with ticl4 in the presence or absence of an internal stereoregulating donor (di-n-butyl phthalate), with different solvents (chlorobenzene, n-undecane, n-heptane) at different titanation temperatures have been studied by a set of physicochemical methods. data on the chemical composition, x-ray structure and pore structure of these ...

Supported catalysts synthesized via the interaction of Mg(OEt)2 with TiCl4 in the presence or absence of an internal stereoregulating donor (di-n-butyl phthalate), with different solvents (chlorobenzene, n-undecane, n-heptane) at different titanation temperatures have been studied by a set of physicochemical methods. Data on the chemical composition, X-ray structure and pore structure of these ...

the data on the effect of ethylene concentration on polymerization rate for several modifications of modern highly active titanium–magnesium catalysts ticl4/mgcl2 are presented. these catalysts differ in titanium content and conditions of support preparation, activities, and the shape of kinetic curves. it is found that the observed order of polymerization rate with respect to ethylene in the r...

the interaction of the external donor (propyltrimethoxysilane - ptms) with titanium-magnesium catalysts (tmcs) containing dibutylphthalate (dbp) as internal donor, which were prepared in different ways, was studied by chemical analysis and infrared diffuse reflectance spectroscopy (drifts). the chemical composition of the catalysts after their interaction with heptane solutions of ptms, ptms/al...

in ziegler-natta olefin polymerization, the pore architecture of catalysts plays a crucial role in catalyticperformances and polymer properties. while the type of preparation routes (such as chemical reaction andsolution precipitation) greatly affects the catalyst pore architecture as a result of different solidification mechanisms,the modification of the pore architecture within a given route ...

The data on the effect of ethylene concentration on polymerization rate for several modifications of modern highly active titanium–magnesium catalysts TiCl4/MgCl2 are presented. These catalysts differ in titanium content and conditions of support preparation, activities, and the shape of kinetic curves. It is found that the observed order of polymerization rate with respect to ethylene in the r...

Polychlorinated benzenes, dibenzo-p-dioxins (PCDD), and dibenzofurans (PCDF) may be formed below the combustion temperature in fly ash from municipal solid waste incinerators (MSWI). Copper catalyzes this formation, possibly by the Deacon reaction. Many other elements are also Deacon catalysts or promoters, and here we report results from a statistically designed experiment with 15 metal oxides...

Data were obtained on the copolymerization of ethylene with α-olefins over supported titanium–magnesium catalysts (TMC) prepared same magnesium dichloride support but differing in composition and oxidation state titanium. The kinetics 1-hexene TMC different compositions studied. produced ethylene–1-hexene copolymers, their molecular weight distribution, thermophysical characteristics, branching...

The interaction of the external donor (propyltrimethoxysilane - PTMS) with titanium-magnesium catalysts (TMCs) containing dibutylphthalate (DBP) as internal donor, which were prepared in different ways, was studied by chemical analysis and infrared diffuse reflectance spectroscopy (DRIFTS). The chemical composition of the catalysts after their interaction with heptane solutions of PTMS, PTMS/Al...

Implant-associated infections commonly result from biofilm‑forming bacteria and present severe complications in total joint arthroplasty. Therefore, there is a requirement for the development of biocompatible implant surfaces that prevent bacterial biofilm formation. The present study coated titanium samples with a thin, rapidly corroding layer of magnesium, which were subsequently investigated...