Utilization of normal and isoparaffins, separately and in mixtures, by a Trichosporon sp. was investigated. From a mixture of normal paraffins and isoparaffins, the organism consumed straight-chain paraffins, leaving the branched paraffins relatively unchanged. When offered separately, the highest utilization of n-alkanes by the organism was obtained in the range of undecane to octadecane; n-pe...

The dynamics of oligomer desorption from surfaces has been studied by measuring the desorption kinetics of a set of straight chain alkanes [ H(CH2)(n)H, with n = 5 to 60] from the surface of single crystalline graphite. Desorption is observed to be a first-order process and the preexponent of the desorption rate constant has a value nu = 10(19.6+/-0.5) sec(-1) and is independent of the oligomer...

The potassium permanganate oxidation of methylated humic acid from a Spanish lignite yielded mainly straight-chain alkanes together with a mixture of fatty acids, methyl straight-chain alkyl ketones, aliphatic dicarboxylic, phenolic and benzenecarboxylic acids. Furthermore, some unusual compounds such as dehydroabietic and bromohydroxybenzoic acids and bis(2-ethylhexyl)phthalate were also ident...

The cuticular hydrocarbons of diapausing pupae of the tobacco hornworm, Manduca sexta (L.), are composed of two types of hydrocarbons: n-alkanes (3%) and unsaturated hydrocarbons (97%). The integument, fat body, muscle, and hemolymph are composed of three types of hydrocarbons: n-alkanes (9, 6, 9, and 2%, respectively), branched alkanes (75, 85, 80, and 56%, respectively), and unsaturated hydro...

The dependence of relative response factors on the carbon atom number related to naphthalene has been investigated in homologous series by using gas chromatography-mass spectrometry. Relative responses of some straight chain aliphatic n-alkanes and their halogenated derivatives (chlorine, bromine and iodine) were compared in the experiments. Linear correlations were found between the molecular ...

An experimental investigation of the characteristics and transformation mechanism Jimsar oil shale derived was conducted using a solid-state nuclear magnetic resonance spectrometer (13C NMR), Fourier transform infrared spectroscopy (FT-IR), liquid 1H NMR, gas chromatography-mass spectrometry (GC-MS) techniques. The carbon skeleton structure is mainly composed aliphatic carbons (70.5%), mostly c...

Acinetobacter sp. strain DSM 17874 is capable of utilizing n-alkanes with chain lengths ranging from that of decane (C10H22) to that of tetracontane (C40H82) as a sole carbon source. Two genes encoding AlkB-type alkane hydroxylase homologues, designated alkMa and alkMb, have been shown to be involved in the degradation of n-alkanes with chain lengths of from 10 to 20 C atoms in this strain. Her...

Additive models for molecular parameters have a long history, and remain important for the rapid prediction of molecular properties. To test the validity of an additive approach, we study the polarizabilities of methyl branched alkanes in the terahertz spectral range, and compare these to the polarizabilities of their straight chain counterparts. A single branched methyl group increases the iso...

Molecular Dynamics (MD) simulations were applied to calculate self-diffusion coefficients (Di ) and heats of adsorption for ethane, propane and n-butane. The simulations were done in temperature range of 300-525 K for various concentrations inside the pores of silicalite type zeolite. The calculated values of self-diffusion coefficients and heats of adsorption resulted from the current wo...