Monodentate phosphoramidite ligands have been developed based on enantiopure 6,6'-dimethylbiphenols with axial chirality. These chiral ligands are easy to prepare and flexible for modifications. The fine-tuning capability of these ligands plays a significant role in achieving high enantioselectivity in the asymmetric hydroformylation of allyl cyanide and the conjugate addition of diethylzinc to...

1Global Energy Systems, Department of Earth Sciences, Uppsala University, Villavägen 16, 752 36 Uppsala, Sweden 2Moscow School of Economics, Moscow State University, Moscow, Russia 3Faculty of Economics, Higher School of Economics, Moscow, Russia 4The International College of Economics and Finance, Higher School of Economics, Moscow, Russia 5Post Peak Living, San Francisco, CA, USA 6Management ...

Tada! Highly functionalized chiral dibenzazepinones are obtained by a mild palladium(0)-catalyzed enantioselective C-H arylation with excellent selectivities by using simple taddol phosphoramidite ligands. The amide tether allows exclusive regioselectivity through a rare eight-membered palladacycle intermediate.

As part of its 100th-anniversary celebration, the Pan American Health Organization has named 12 persons as "Public Health Heroes of the Americas" in recognition of their noteworthy contributions to public health in the Region of the Americas. Over the course of this year, the Revista Panamericana de Salud Pública/Pan American Journal of Public Health will be carrying pieces written by or about ...

this study was performed to determine the effect of injecting selenium into pregnant heifers at the last stage of gestation on the serum se, cu, zn and fe status of the heifers and their calves. fifty holstein heifers were randomly assigned to one of five treatments. four and two weeks before the expected time of calving, the heifers were injected intramuscularly 10 ml (t1), 20 ml (t2), 30 ml (...

In the previous paper of this series, the retention characteristics of 4-methyl sterols were investigated with a view for establishing a systematic relationship between the structure of sterols and their gas chromatographic characteristics. The present report deals an extended study on 6methyl sterols prepared from cholesterol. The retention data for five 6-methyl sterols and for their derivati...

Povzetek. Sodobne organizacije se spreminjajo zelo pogosto. Spremembe se poskuša izvesti hitro in učinkovito. Spremembe pogosto vključujejo spremembe IS zaradi njegovega pomena v organizacijah. Odpor do sprememb spada med ključne dejavnike uspeha večjih projektov in programov IT. Obvladovanje odpora ne pomaga organizacijam zgolj izvesti spremembe hitreje in učinkoviteje, temveč je hkrati tudi p...

Objectives: to translate, adapt cross-culturally and validate into Brazilian Portuguese the following instrument: "Self-assessment of communication skills and professionalism in residents" for the nursing professional, and to determine if personal characteristics and performance of the nurse interfere in the self-assessment about professionalism and interpersonal communication. Method: quanti...

Modular chiral dendrimers with monodentate phosphoramidite ligands located at the core were synthesized and applied in the Rh-catalyzed asymmetric hydrogenations, afforded unprecedented enhancement of enantioselectivity.