electrode potential of 2-(2,3-dihydroxy phenyl)-1,3-dithiane (dpd) was investigated by means of cyclic voltammetry (cv) at various potential scan rates. the calculated value was compared with the experimental value obtained by cyclic voltammetry (cv). all experiments were done in aqueous phosphate buffer solutions at different phs. the experimental redox potential of dpd was obtained to be 0.75...

Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 complex was prepared according to literature report. The reaction between aforementioned complex via sodium alkoxides as a reactants, were carried out in the solid state. The [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 undergoes an intramolecular two electrons oxidation-reduction reaction at room temperature and metallic nickel nanoparticles (Ni1-Ni5) was ...

ni6(n2h4)6(so4)4(oh)2(h2o)8](so4)(h2o)10 complex was prepared according to literature report. the reaction between aforementioned complex via sodium alkoxides as a reactants, were carried out in the solid state. the [ni6(n2h4)6(so4)4(oh)2(h2o)8](so4)(h2o)10 undergoes an intramolecular two electrons oxidation-reduction reaction at room temperature and metallic nickel nanoparticles (ni1-ni5) was ...

ni6(n2h4)6(so4)4(oh)2(h2o)8](so4)(h2o)10 complex was prepared according to literature report. the reaction between aforementioned complex via sodium alkoxides as a reactants, were carried out in the solid state. the [ni6(n2h4)6(so4)4(oh)2(h2o)8](so4)(h2o)10 undergoes an intramolecular two electrons oxidation-reduction reaction at room temperature and metallic nickel nanoparticles (ni1-ni5) was ...

A complement to the classic three-component Mannich reaction, the redox-Mannich reaction, utilizes the same starting materials but incorporates an isomerization step that enables the facile preparation of ring-substituted β-amino ketones. Reactions occur under relatively mild conditions and are facilitated by benzoic acid.

in this work the kinetic data demanded for kinetic modeling were obtained in temperatures 350, 400, 450 and 500 oc by conducting experimentations on a fe-cr nanocatalyst prepared from a novel method and a commercial fe-cr-cu one. the collected data were subjected to kinetic modeling by using two models derived from redox and associative mechanisms as well as an empirical one. the coefficients o...