volumetric techniques were employed to study the adsorption of co2 on a purified multi-wall carbon nanotubes (mwnt’s) sample, as a mesoporous material, at isothermal conditions of 288, 293 and 298 k and pressures ranging from 30 to 150 kpa. langmuir, freundlich and sips equations were used to represent the isotherms. also the parameters of these fitted isotherm models have been determined. the ...

cycloaddition reaction between c30 and hula-i, 3-diene was studied within the snimework of am i (rhf)level. the reaction involving the double bond between two hexagons and a hexagon and a pentagon, as wellas the cycloaddition products followed by disrotatory ogs s electrocyclic ring openings were considered.thermodynamics parameters and stability energy and innsation state are evaluated in thre...

chemical vapor deposition was employed to synthesize carbon nanotubes with ni-loaded mcm-41 and mcm-48 as catalysts and acetylene as precursor at 750°c. mesoporous ni mcm-41 and ni mcm-48 molecular sieves were synthesized by a hydrothermal method and were characterized by xrd and n2 adsorption isotherm. the catalytically synthesized carbon materials were characterized with raman spectroscopy, n...

copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [cu3(btc)2] (1) and [cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400,  500, and 600°c. it has also been found that the reaction temperature pla...

aluminum sulfate nano structures have been prepared by solution combustion synthesis using aluminum nitrate nonahydrate (al(no3)3.9h2o) and ammonium sulfate ((nh4)2so4). the resultant aluminum sulfate nano structures were calcined at different temperatures to study thermal  decomposition of aluminum sulfate. the crystallinity and phase of  the as-synthesized and calcined samples were characteri...

The resputtering of gold films from nano-holes defined in a sacrificial PMMA mask, which was made by electron beam lithography, was carried out with a dry plasma etching tool in order to form well-like structures with a high aspect ratio (height/width ≈ 3-4) at the rims of the nano-holes. The extraordinary transmission through the patterns of such nano-wells was investigated experimentally and ...

a facile and simple method was proposed to control the size and shape of the mgo nano structures with high surface area in the presence of efficient and cheap templates like peg 200, peg 600, peg 4000 and sorbitol at low temperature within a little time. nano rods and nanoparticles have been achieved by applying these templates and altering other growth parameters. the products were characteriz...