The metal chloride of LaCl3 was chosen to modify the Au-Cu/AC to decrease the noble metal of gold and enhance the catalytic performances. Then a mercury-free catalyst of Au-Cu-La/AC was prepared by the impregnation method, and the fresh Au-Cu-La/AC and Au-Cu/AC catalysts were also characteri...

Since its discovery in the 1920s, the Fischer-Tropsch Synthesis (FTS) has undergone periods of rapid development and periods of inaction. Within ten years of the discovery, German companies were building commercial plants. The construction of these plants stopped about 1940 but existing plants continued to operate during WWII. Two types of reactors were used in the German commercial plants: the...

Heat and mass transfer problem in a fixed-bed tubular reactor is one of the major concerns in the chemical engineering. The two dimensional axial plug flow model was used for a water gas shift reactor to compare heat conduction or mass diffusion with convective effect. In the case of fast fluid flow in highly permeable catalyst-bed, convective heat transfer was dominant compared to heat conduct...

Styrene is an important monomer in the manufacture of thermoplastic. Most of it is produced by the catalytic dehydrogenation of ethylbenzene. In this process that depends on reversible reactions, the yield is usually limited by the establishment of thermodynamic equilibrium in the reactor. The styrene yield can be increased by using a hybrid process, with reaction and separation simultaneously....

in this study the catalytic dehydrogenation of ethylbenzene to styrene was investigated in a simulated tubular sodalite membrane reactor. the high quality microporous sodalite membrane was synthesized by direct hydrothermal method and characterized by single gas permeation measurements. the performance of the prepared membrane showed high potential for application in a dehydrogenation membrane ...

ethyl benzene used increasingly each year is the raw material of producing styrene monomer. this substanceis produced from benzene alkylation with ethylene or ethanol, depending on the availability and cost of rawmaterials. in this study benzene alkylation in the presence of ethanol in a catalytic fixed bed reactor inthree states of isotherm, adiabatic and non-isotherm-non-adiabatic is mathemat...

in a novel dual bed reactor fischer-tropsch synthesis was studied by using two diffrent cobalt catalysts. an alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a rutenuim promoted cobalt catalyst in the second bed. the activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed react...

background: the modeling aims to simulate or optimize a process in physical, chemical or biological environments and the derived model will provide a considerable assistance to generate data and predict unknown condition, in case of sufficient suitability. unsuitable disposal and elimination of waste tires have polluted the environment and human life areas, it also have caused removal of a huge...

in this research, the selective oxidation of benzene to maleic anhydride (man) in a fixed-bed reactor was studied. the gas phase catalytic oxidation of benzene was carried outin a laboratory scale fixed bed reactor on the catalysts, which were prepared having two different compositions on silica gel. the effects of temperature, flow rates of benzene and air, and catalyst type on the reaction se...