A glassy carbon, P3, obtained by carbonization of polyfurfuryl alcohol was used to study the changes produced by oxygen plasma treatments which were compared to those obtained by molecular oxygen. The sample was selected for its well defined mesoporosity. The aim was to study the influence of porosity on the reactivity of the sample in oxygen plasma. The results were compared to previously repo...

The rate of hydration influences many important physical properties of gypsum. Previous research examined the rate of gypsum hydration and related this to compressive strength and microstructure development using BET specific surface area analysis. The analysis of gypsum porosity in combination with BET surface area and rate of hydration remains to be done. In the present study, mesoporosity is...

S are a unique type of high-power electrochemical energy storage devices being developed for a wide range of applications, including consumer electronics, medical electronics, electrical utilities, transportation, and military defense systems. However, the energy and power densities, safety, and cycle life of currently available supercapacitors need to be significantly improved to satisfy the r...

Two SiO2 and three Al2O3 adsorbents with varying degrees of mesoporosity (pore diameter 2-50 nm) were reacted with 2,4-dichlorophenoxyacetic acid (2,4-D) at pH 6 to investigate the effects of intraparticle mesopores on adsorption/desorption. Anionic 2,4-D did not adsorb onto either SiO2 solid, presumably because of electrostatic repulsion, but it did adsorb onto positively charged Al2O3 adsorbe...

Flexible, magnetic, and hierarchical porous NiFe2O4@SiO2 nanofibrous membranes were prepared by combining the gelatin method with electrospun nanofibers. The membranes exhibited prominent mechanical strength and mesoporosity, as well as multifunctionality of magnetic responsiveness, dye adsorption, and emulsion separation.

Alternative energy technologies are greatly hindered by significant limitations in materials science. From low activity to poor stability, and from mineral scarcity to high cost, the current materials are not able to cope with the significant challenges of clean energy technologies. However, recent advances in the preparation of nanomaterials, porous solids, and nanostructured solids are provid...

Conversion of propanal to gasoline-range molecules was investigated over a series of HZSM-5 catalysts with controlled mesoporosity generated by desilication. Characterization of the structure of the solid by powder X-ray diffraction (XRD), scanning electronic microscopy (SEM), ammonia and isopropylamine temperature programmed desorption (TPD), and n-butane diffusivity measurements confirmed the...

Frameworks of precisely defined pores with diameters matching the size of small molecules endow crystalline zeolites with valuable size- and shape-selectivity. Being important selective adsorbers and separators, zeolites are also indispensable as solid acids in size-selective catalysis. However, despite being extremely beneficial, micropores impose restrictions on the mass transport of reactant...