نتایج جستجو برای: isotherm’s model
تعداد نتایج: 2107408 فیلتر نتایج به سال:
gaz-angubin is a sweet exudate naturally produced by an insect from the gavan-e-gaz-angubin plant. adsorption and desorption isotherms for a gaz-angubin sample were determined at 15° and 25°c over a range of relative humidity from 0 to 90% using a dynamic vapor sorption system. at different levels of relative humidity, changes in sample mass were continuously measured versus time and described ...
Activated carbons are disorganized materials with variable pore size distributions (PSD). If one assumes that the porosity consists mainly of locally slit-shaped micropores, model isotherms can be obtained by computer simulations and used to assess the PSD on the basis of experimental isotherms. In the present study, CO isotherms have been measured at 273 K on 2 seven well-characterized micropo...
As part of our efforts to model enhanced coalbed methane recovery and CO2 sequestration in coalbeds, we have investigated the pure adsorption isotherm behavior of five dry coals namely, Illinois #6, Wyodak sub-bituminous, Pocahontas, Beulah Zap, and Upper Freeport coal. Using a volumetric technique, isotherms of pure methane, nitrogen, CO2 and ethane were measured at a temperature of 328.15 K (...
The close link between the roughness of a surface and its adsorptive properties in Cerofolini’s model yields, with an adequate choice adsorption energy, well-known Dubinin-Radushkevich or Freundlich isotherms. Assuming fractal behavior concerning both energetic geometric heterogeneities described by power-law expressions dimensions, paper will develop some Using our theoretical approach, isothe...
Carbon dioxide adsorption isotherms have been computed for the Metal-Organic Framework (MOF) Fe2(dobdc), where dobdc4− = 2,5-dioxido-1,4-benzenedicarboxylate. A force field derived from quantummechanical calculations has been used to model adsorption isotherms within a MOF based on a parameterization scheme. Restricted Open-shell Møller-Plesset second-order perturbation theory (ROMP2) calculati...
methyl orange is one dye resulted from the textile industry. the aim of this study is to test theadsorption capacity of nickel oxide nanoparticles for removing the methyl orange from aqueoussolution. the parameters studied were the effect of temperature, contact time and initial ph ofsolution. results indicate that the removal efficiency of nickel oxide nanoparticles increases withincreasing co...
organic acids exuded by plant roots increase solubility of soil micronutrient complexes. this study was carried out to evaluate adsorption isotherms of 4 acidic and 4 calcareous soils at presence of organic acids (citric, malic and oxalic acids). iron sorption and desorption isotherms are defined in to two systems including; system 1; soil-water-metal, system 2; soil-water-organic acid-metal). ...
A model of the capillary condensation process, i.e., of adsorption-desorption isotherms, having only porepore interactions is constructed. The model yields ~1! hysteretic isotherms, ~2! invasion percolation on desorption, and ~3! hysteresis with discrete memory for interior chemical potential loops. All of these features are seen in experiment. The model is compared to a model with no pore-pore...
The adsorption behaviour of Methyl violet and Auramine yellow from aqueous solution onto Stishovite clay was investigated as a function of parameters such as initial dye concentration, contact time, p and temperature. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. Adsorption followed pseudo-second order model. The experimental data fitted well ...
Biosorption of uranium metal ions by a nonliving protonated Sargassum fluitans seaweed biomass was used to remove the heavy metal uranium from the aqueous solution. Uranium biosorption isotherms were established for solution pH values ranging from pH 2.5-4.0. Uranium biosorption uptake was accompanied by the release of protons from the biomass. The sorption isotherms were highly pH dependent, a...
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