the kinetics of hydrogen evolution reaction (her) was studied in 1m naoh at various temperatures (298 to 358 k) on ni-p-c (composite electrodes. the electrochemical efficiency of the electrodes has been evaluated on the basis of electrochemical data obtained from the steady-state polarization tafel curves, electrochemical impedance spectroscopy (eis) and cyclic voltammetry (cv) in 1m naoh solut...

In this study Ni catalyst have been activated during hydrogen evolution reaction (HER) by adding Mo ions into the alkaline electrolyte. After dissolving different amounts of ammonium molybdate in the 1M NaOH as electrolyte, Ni catalyst was used as cathode for HER. Afterwards a comparison between hydrogen overpotential measured in Ni catalyst with and without in situ activation has been made; th...

In the present work, Pd, Rh and PdRh nanoparticles (NPs) were synthesized in a deep eutectic solvent (DES) by electrodeposition onto glassy carbon substrate. The NPs evaluated for hydrogen evolution reaction (HER, Hydrogen Evolution Reaction), an acid medium. results showed that highest catalytic activity HER was metallic Rh.

hydrogen is considered as a unique choice for future world’s resources. the important parameter in the process of hydrogen production is the value of reduction potential for the used catalyst, in direct contact with consumed energy in process. the application of computational methods to design and modify molecular catalysts is highly regarded. this study sought to explore density functional the...

The kinetics of hydrogen evolution reaction (HER) was studied in 1M NaOH at various temperatures (298 to 358 K) on Ni-P-C (composite electrodes. The electrochemical efficiency of the electrodes has been evaluated on the basis of electrochemical data obtained from the steady-state polarization Tafel curves, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) in 1M NaOH solut...

Developing inexpensive and highly efficient non-precious-metal electrocatalysts has been proposed as a promising alternative to platinum-based catalysts for the hydrogen evolution reaction (HER). Herein, we report novel FeP NPs supported on inexpensive and available candle soot (FeP-CS) derived from Fe3O4-CS hybrid precursors obtained after a phosphidation reaction. As HER electrocatalysts, the...

Tungsten oxide/tungsten sulfide (W18O49@WS2) core-shell nanorods prepared via a controlled sulfidization reaction of W18O49 nanowhiskers showed hydrogen evolution reaction (HER) activity superior to WS2 nanotubes, indicating the critical role of a highly conductive oxide core in enhancing HER activity.