The influence of hydrazine reduction on metal dispersion, particle size distribution, and support morphology was investigated for a series of bimetallic Ru-AuiMgO catalysts. The catalysts were prepared by impregnation of MgO with chlorine-containing precursor salt solutions. Hydrazine reduction significantly lowered the residual chlorine content of the catalysts and allowed the formation of hig...

in this paper, multivariate calibration methods of partial least squares (pls) and principle component regression (pcr) were investigated in simultaneously determination of hydrazine (hz) and acetylhydrazine (ahz). the aforementioned methods are based on formation of the silver nanoparticles (agnps) from the reaction of hz and ahz with ag+ ions as oxidizing agent in the presence of citrate ions...

Sir: As part of our effort aimed at the synthesis of new rifamycin derivatives,1) the 3-hydrazino derivatives of rifamycin S (2) and SV (3) have been obtained by treating 3-bromorifamycin S (1a) with isopropylidene-methyl hydrazine and with isopropylidene-methyl hydrazine followed by hydrazine, respectively.2) We wish to describe here a novel rearrangement of the ansa bridge under acidic condit...

In this paper, multivariate calibration methods of partial least squares (PLS) and principle component regression (PCR) were investigated in simultaneously determination of hydrazine (HZ) and acetylhydrazine (AHZ). The aforementioned methods are based on formation of the silver nanoparticles (AgNPs) from the reaction of HZ and AHZ with Ag+ ions as oxidizing agent in the presence of citrate ions...

While researchers have extensively studied the initial decomposition mechanism of Monomethylhydrazine (MMH, CH3NHNH2) in MMH/dinitrogen tetroxide (NTO) system, investigation Unsymmetrical Dimethylhydrazine (UDMH, (CH3)2NNH2) has been limited due to its high toxicity, corrosiveness, and deterioration rate. Hence, effects UDMH’s products on combustion performance gas-phase reaction mechanisms rem...

We have developed a simple and selective method for the electrochemical detection of hydrazine (HZ) using poly(dopamine) (pDA)-modified indium tin oxide (ITO) electrodes. Modification with pDA was easily achieved by submerging the ITO electrode in a DA solution for 30 min. The electrocatalytic oxidation of HZ on the pDA-modified ITO electrode was measured by cyclic voltammetry. In buffer soluti...

Mutagenesis is a highly efficient tool for establishing genetic variation and widely used enhancement in various plants. The key benefit of mutation breeding the prospect enhancing one or several characteristics variety without altering background. In this study, we exposed seeds Salvia officinalis to four concentrations hydrazine hydrate (HZ), i.e., (0%, 0.1%, 0.2%, 0.3%) 6 h. contents terpeno...

The present study describes the application of simultaneous kinetic spectrophotometric determination of hydrazine (HZ) and isoniazid (INH), using H-point standard addition method (HPSAM) and partial least squares (PLS) calibration. The methods are based on the difference observed in the rate of iron (III) reduction with HZ and INH, in the presence of 2,2'-bipyridine (Bpy) and the subsequent com...

A U-shaped conformation is found in the title compound, C(19)H(21)N(3)O(5), with the benzene rings lying to the same side of the mol-ecule; the dihedral angle between them is 10.83 (16)°. The dihedral angle formed between the hydrazinecarbonyl and carbamate residues is 68.42 (13)°. The carbonyl groups lie approximately at right angles to each other [O-C⋯C-O pseudo torsion angle of 107.7 (3)°], ...

The through-thickness electric permittivity (real part) of the solid part (53 vol%) of reduced graphite oxide (RGO) paper (100e300 mm thick, prepared by hydrazine reduction of modified-Hummers-method graphite oxide, GO) is 1130 (50 Hz), which is higher than that of the similarly tested parent GO (915, 50 Hz) and other carbons (31e124, 50 Hz). The high permittivity of RGO is attributed to the de...