نتایج جستجو برای: gd(iii) complex

تعداد نتایج: 783868  

Journal: :Journal of the American Chemical Society 2006
Matthew J Allen Ronald T Raines Laura L Kiessling

A monomer for ring-opening metathesis polymerization (ROMP) has been developed that also functions as a portion of a GdIII chelating moiety for a magnetic resonance imaging contrast agent. An increase in per GdIII relaxivity was shown upon transition from monomer to polymer. Additionally, extremely large molecular relaxivities were achieved through incorporation of multiple GdIII ions per polym...

Journal: :Dalton transactions 2005
Satoru Ikeda Toshiya Hozumi Kazuhito Hashimoto Shin-Ichi Ohkoshi

In this paper, we report the crystal structure and magnetic properties of the cyano-bridged gadolinium-tungstate bimetallic assembly, GdIII(DMF)6[WV(CN)8](DMF =N,N-dimethylformamide). X-Ray single crystal analysis shows that this compound crystallizes in the monoclinic system of space group P2(1)/c with cell constants a= 16.40(2)A, b= 11.08(1)A, c= 21.18(2)A, beta= 91.09(8) degrees, and Z= 4. T...

Journal: :Journal of the American Chemical Society 2003
Marlon K Thompson Mauro Botta Gaëlle Nicolle Lothar Helm Silvio Aime André E Merbach Kenneth N Raymond

The stability and water exchange dynamics of gadolinium (GdIII) complexes are critical characteristics that determine their effectiveness as contrast agents for magnetic resonance imaging (MRI). A new heteropodal GdIII chelate, [Gd-TREN-bis(6-Me-HOPO)-(TAM-TRI)(H2O)2] (Gd-2), is presented which is based on a hydroxypyridinate (HOPO)-terephthalamide (TAM) ligand design. Thermodynamic equilibrium...

2004
Ayhan Elmali

The crystal structure and the magnetic properties of a heterodinuclear complex, [LCu(Me2CO)Gd(NO3)3]2 (L=N,N’-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) are reported: [(C19H20N2O4)Cu(C3H6O)Gd(NO3)3]2, triclinic, space group P1, with a = 12.118.3(9), b = 13.562(3), c = 9.391(3) Å, α = 93.03(3), β = 107.65(2), γ = 73.07(2)◦ , V = 1406.0(7) Å3, Z = 1. The crystal structure consists of...

Journal: :Acta Crystallographica Section A Foundations of Crystallography 2000

2004
Nicolas Fatin-Rouge Eva Tóth Réto Meuli Jean-Claude G. Bünzli

MRI contrast properties of self-aggregated nanoparticles made from GdIII and 1,2,4,5-tetrakis(pyrazol-1-yl-methyl-3-carboxylate)benzene (L) are investigated. Viscosity of GdL2 suspensions and size-characteristics of GdL2 nanoparticles allow an estimate of their large rotational correlation time. Moreover, two to three H2O molecules are bound, on average, to GdIII ions, as deduced from 17O NMR t...

2017
Wuyuan Zhang Jonathan Martinelli Joop A Peters Jacob M A van Hengst Hans Bouwmeester Evelien Kramer Célia S Bonnet Frédéric Szeremeta Éva Tóth Kristina Djanashvili

Surface PEGylation of nanoparticles designed for biomedical applications is a common and straightforward way to stabilize the materials for in vivo administration and to increase their circulation time. This strategy becomes less trivial when MRI active porous nanomaterials are concerned as their function relies on water/proton-exchange between the pores and bulk water. Here we present a compre...

Journal: :Angewandte Chemie 2023

Studies of protein structure and dynamics are usually carried out in dilute buffer solutions, conditions that differ significantly from the crowded environment cell. The double electron-electron resonance (DEER) technique can track proteins’ conformations cell by providing distance distributions between two attached spin labels. This technique, however, cannot access distances below 1.8 nm. Her...

Journal: :Dalton transactions 2017
Thomas N Hooper Stuart K Langley Silvia Gómez-Coca Giulia Lorusso Eliseo Ruiz Keith S Murray Marco Evangelisti Euan K Brechin

The syntheses, structures, magnetic and thermodynamic properties of three related triethanolamine-based GdIII complexes are described. The smallest, a dimer ([Gd2]), can be viewed as the subunit from which the two larger complexes, a linear tetramer ([Gd2]2) and a cyclic hexamer ([Gd2]3), are composed by further deprotonation of the triethanolamine ligand. In all cases, nearest neighbour magnet...

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