in this paper the density and temperature dependencies of surface tension are investigated. using the lennard-jones (12,6), as an effective pair interaction potential, a linear expression is derived for isotherms of g /r2  versus r2 for some normal and chlorofluorocarbons (cfcs) fluids, where  is surface tension and r = 1/v is molar density. the linearity behavior of the derived equation is wel...

In this paper, the vapor-liquid equilibrium (VLE) properties of polar and nonpolar fluids are modeled by the use of a statistically-based equation of state (EOS). The equation of state used in this work is that of Ihm-Song-Mason (ISM) EOS. An alternative approach is to revise the isothermal integration on liquid. In this respect, a temperature-dependent revision factor b (T) is introduced to th...

An analytical equation of state has been previously modified by Papari et al. for representing the volumetric properties of molecular fluids. However the performance of that EOS has not been yet well investigated for refrigerant fluids. This study extended that equation to 19 liquid refrigerants to predict their densities at isothermal and saturated states. Two temperature-independent parameter...

an extended peng-robinson equation of state (epr-eos) is used to model the vapor-liquid equilibrium (vle) in systems containing (water + nacl + co2), (water + methanol + nacl + co2), (water + na2so4 + co2) and (water + nh4cl + co2). the binary and ternary interaction parameters between salt and solvent are adjusted to experimental mean solvent activity of salts (nacl and na2so4). for the system...

alkanolamine solutions such as 2-amino-2-methyl-1-propanol (amp) are widely used in chemical industries for the removal of acid gases such as co2 and h2s. in this work, the density of co2, amp, water, and amp solutions using the goharshadi–morsali–abbaspour equation of state “gma eos” in the extended 50-degree range of temperatures (313.06-362.65 k) and pressures (0.5-40 mpa) was calculated. th...

an analytical equation of state has been previously modified by papari et al. for representing the volumetric properties of molecular fluids. however the performance of that eos has not been yet well investigated for refrigerant fluids. this study extended that equation to 19 liquid refrigerants to predict their densities at isothermal and saturated states. two temperature-independent parameter...

in this paper, the vapor-liquid equilibrium (vle) properties of polar and nonpolar fluids are modeled by the use of a statistically-based equation of state (eos). the equation of state used in this work is that of ihm-song-mason (ism) eos. an alternative approach is to revise the isothermal integration on liquid. in this respect, a temperature-dependent revision factor b (t) is introduced to th...

Herein, the application of Carnahan-Starling-vdW-β equation of state (EoS) for 13 refrigerant fluids was investigated. The EoS could predict the saturated liquid densities of these refrigerants over the temperature range of 100-400 K and pressures from zero up to187 MPa with the average absolute deviations of 2.66%. The accuracy of Carnahan-Starling-vdW-β EoS in liquid density prediction was al...

calculate some thermodynamic properties of molten polymers including specific volume and isothermal compressibility (s.m. hoseini, physical chemistry & electrochemistry, 2 (2014) 56-65). this work extended that eos to predict the volumetric properties of some molten ethylene copolymers including ethylene/1-octene, ethylene/1-butene (xethylene equal to 0.8543 and 0.563), ethylene/propene. the ab...