In this work, the practicality of catalytic surfaces of nano-structured Co3O4 and MnCo2O4 for the adsorption and neutralization reactions of dimethyl methyl phosphonate (DMMP) as an toxic agricultural organo-phosphorous pesticide has been investigated. The Co3O4 and MnCo2O4 NPs have been successfully prepared by precipitation method using cobalt nitrate and manganese nitrate as the precursors a...

in this work, the practicality of catalytic surfaces of nano-structured co3o4 and mnco2o4 for the adsorption and neutralization reactions of dimethyl methyl phosphonate (dmmp) as an toxic agricultural organo-phosphorous pesticide has been investigated. the co3o4 and mnco2o4 nps have been successfully prepared by precipitation method using cobalt nitrate and manganese nitrate as the precursors a...

1-5 Napthalenedisulphonic acid (NDSA) doped polypyrrole thin films are prepared by chemical oxidation polymerization and applied as modified claddings to optical fibers for organophosphate (dimethyl-methyl phosphonate, DMMP) sensing. DMMP sensing takes place via intensity modulation in multimode fibers due to refractive index modulation in polypyrrole films due to DMMP adsorption. The polypyrro...

A novel gas sensor consisting of porous, non-stacked reduced graphene oxide (NSrGO)-heaxfluorohydoroxypropanyl benzene (HFHPB) nanosheets was successfully fabricated, allowing the detection of dimethyl methyl phosphonate (DMMP), similar to sarin toxic gas. The HFHPB group was chemically grafted to the NSrGO via a diazotization reaction to produce NSrGO-HFHPB. The NSrGO-HFHPB 3D film has a mesop...

Chemical warfare agents (CWAs) are highly toxic and fast-acting easy to cause large-scale poisoning humans livestock after being released. The activated carbon used for CWAs adsorption has disadvantages of limited capacity, aging deactivation. Metal oxides have environmental stability, they characterized by long lasting broad spectrum when thermal catalytic decomposition. Therefore, in this stu...

This paper investigates the determination of the concentration of a chemical vapor as a function of several nonspecific microcantilever array sensors. The nerve agent dimethyl methyl phosphonate (DMMP) in parts-per-billion concentrations in binary and ternary mixtures is able to be resolved when present in a mixture containing parts-per-million concentrations of water and ethanol. The goal is t...

A band gap tuning of environmental-friendly graphene quantum dot (GQD) becomes a keen interest for novel applications such as photoluminescence (PL) sensor. Here, for tuning the band gap of GQD, a hexafluorohydroxypropanyl benzene (HFHPB) group acted as a receptor of a chemical warfare agent was chemically attached on the GQD via the diazonium coupling reaction of HFHPB diazonium salt, providin...

The thermochemistry and kinetics of organophosphorus compounds were studied, with BAC-MP4 method estimations as a basis and PM3 semi-empirical estimations for many new compounds. New group additivity values were proposed for enthalpies of formation at 298 K, and entropies and heat capacities of species involving pentavalent phosphorus bonded to carbon, hydrogen, oxygen, fluorine, nitrogen, and ...

In this work, ZnCaO2 (zinc oxide-calcium oxide) nanocomposite were synthesized at different temperatures (500-700°C) by sol-gel method based on polymeric network of polyvinyl alcohol (PVA). The synthesized samples were characterized by SEM/EDAX, FT-IR and XRD techniques. It was found that synthesized nanocomposites have 1.62, 2.05 and 13.91%wt of CaO, respectively. The obtained results show tha...

In this work, ZnCaO2 (zinc oxide-calcium oxide) nanocomposite were synthesized at different temperatures (500-700°C) by sol-gel method based on polymeric network of polyvinyl alcohol (PVA). The synthesized samples were characterized by SEM/EDAX, FT-IR and XRD techniques. It was found that synthesized nanocomposites have 1.62, 2.05 and 13.91%wt of CaO, respectively. The obtained results show tha...