zn-co electrodeposits have attracted interest because of their significantly higher corrosion resistance in comparison with pure zinc. in this research the influence of bath temperature and electrolyte’s co 2+ concentration on the morphology and composition of the zn-co coatings, electrodeposited on an aisi1018 steel substrate from a weakly alkaline glycine solutions, has been studied. sem and ...

methanol steam reforming plays a pivotal role to produce hydrogen for fuel cell systems in a low temperature range. to accomplish higher methanol conversion and lower co production, the reaction was catalyzed by cuznfe mixed oxides. various ratios of fe and cu/zn were coprecipitated in differential method to optimize the cuznfe structure. the sample containing 45cu50zn5fe (wt. %) revealed its m...

a r t i c l e i n f o Zn–Ni, Zn–Co and Zn–Ni–Co coatings were electrodeposited on mild steel from an acidic chloride bath containing p-aminobenzenesulphonic acid (SA) and gelatin. These additives changed the phase content in the coatings, most likely as a result of their adsorption at the surface of the cathode. The effect of gelatin was more pronounced than that of SA. The Faradaic efficiency ...

Recently, a combined laser ablation and density functional theory study (Jiang and Xu, J. Am. Chem. Soc. 2005, 127, 8906) claimed the existence of the long-sought 18-electron member of the first-row transition metal carbonyl complex, Zn(CO)(3). In this paper, we systematically investigate the thermodynamic and kinetic stability of Zn(CO)(3) towards CO-extrusion at the BP86, B3PW91, BPW91, PBEPB...

Structural and magnetic properties of a series of low doped Zn 1−x Co x O thin films deposited from Zn and Co metal targets on (0001) Al 2 O 3 substrates. Abstract We report on the synthesis of low doping Zn 1−x Co x O (0 < x < 0.1) thin films on (0001)-Al 2 O 3 substrates. The films were prepared in an oxidizing atmosphere, using the pulsed laser deposition technique starting from Zn and Co me...

Complex metal-organic frameworks used as precursors allow design and construction of various nanostructured functional materials which might not be accessible by other methods. Here, we develop a sequential chemical etching and sulfurization strategy to prepare well-defined double-shelled zinc-cobalt sulfide (Zn-Co-S) rhombic dodecahedral cages (RDCs). Yolk-shelled zinc/cobalt-based zeolitic im...

The inactivation of the Zn+2 metallo enzyme acylamino acid amido hydrolase from Aspergillus oryzae by ethylendiamine-tetraacetate (EDTA) and nitrilotriacetate (NTA) and the effects of Phe and His on this process were studied. Reactivation of the enzyme by Zn+2or Co+2-NTA buffer revealed a dissociation constant for the Zn+2-enzyme of 10~10 M and for the Co+2-enzyme of 10-7-5 m. The kinetic prope...

Objectives: To clarify the role of trace elements in the etiology and the pathogenesis of the osteogenic sarcoma (osteosarcoma), a non-destructive neutron activation analysis with high resolution spectrometry of long-lived radionuclides was performed. Methods: The silver (Ag), cobalt (Co), chromium (Cr), iron (Fe), mercury (Hg), rubidium (Rb), antimony (Sb), selenium (Se), and zinc (Zn) mass fr...