using the gaussian 2003 software and mp2/ 6–311 ++ g** method for he: he, ne:ne andmp2/6-31g method for ar: ar, kr: kr and hf/sto-3g method for xe: xe, the optimizedinteraction energies between two like atoms of rare gases (he, ne, ar, kr and xe) as a functionof the distances between the centers of two considered atoms were evaluated and the resultswere interpreted according to the lennard – jo...

to get a mole of a gas, it is necessary to calculate the intermolecular interaction. theseintermolecular interactions can be depicted by drawing the potential energy of a pair molecule inrelation to the distance. the intermolecular potential energy surface in the mixtures of ch4-h2cogases from ab initio calculations has been explored. in ab initio calculations the basis setsuperposition error (...

We present results for the fourth virial coefficient of quadrupolar Lennard-Jones diatomics for several quadrupole moments and elongations. The coefficients are employed to predict the critical properties from two different truncated virial series. The first one employs the exact second and third virial coefficients, calculated in our previous work. The second includes also the exact fourth vir...

We show that Haldanes new definition of statistics, when generalised to infinite dimensional Hilbert spaces, is equal to the high temperature limit of the second virial coefficient. We thus show that this exclusion statistics parameter, g , of anyons is non-trivial and is completely determined by its exchange statistics parameter α. We also compute g for quasiparticles in the Luttinger model an...

We have computed by a Monte Carlo method the fourth virial coefficient of free anyons, as a function of the statistics angle θ. It can be fitted by a four term Fourier series, in which two coefficients are fixed by the known perturbative results at the boson and fermion points. We compute partition functions by means of path integrals, which we represent diagrammatically in such a way that the ...

Composition-gradient multi-angle static light scattering (CG-MALS) is an emerging technique for the determination of intermolecular interactions via the second virial coefficient B22. With CG-MALS, detailed studies of the second virial coefficient can be carried out more accurately and effectively than with traditional methods. In addition, automated mixing, delivery and measurement enable high...