Shallow buried and unsymmetrically loaded tunnel is the most common type of mountain portal. Currently, studies mainly focus on stability side slope, while investigation deformation front slope after excavation relatively less. In this paper, influence gradient angle between portal was analyzed by FLAC3D. The results show that: When greater than 40°, caused larger with increase angle. order to ...

This study investigated the vault settlement characteristics of an unsymmetrically loaded tunnel which was excavated by annular excavation via core rock support method. Response surface methodology (RSM) was employed to design the experiments, evaluate the results with the purpose of optimizing the value of design parameters for reducing the vault settlement. The parameters such as horizontal d...

We have described the synthesis of novel biphenylethane-based wires for molecular electronics. Exceptional single-molecule diode behavior was predicted for unsymmetrically substituted biphenylethane derivatives, synthesized here using the so far unexplored unsymmetrically substituted 1,2-bis(4-bromophenyl)ethanes as key intermediates, which were obtained from the corresponding tolane precursor ...

Pd nanoparticles generated in green reaction media (viz. ionic liquids and water) catalyze the one-pot sequential Heck and Suzuki coupling reactions of bromo-chloroarenes to afford unsymmetrically substituted arenes in good yields.

The current study compared tunnel diameter as an independent risk factor for fixation failure from the coracoid after transcoracoid coracoclavicular reconstruction. The effect of variation in coracoid size and scapular bone density on fixation failure was also studied. Sixty-two cadaveric scapulae were randomized into 1 of 4 groups: a control group with no coracoid hole, a group with a 4-mm tra...

Microwave assisted CpCo(CO)(2) catalyzed cross-cyclotrimerizations of 1,7,9,15-hexadecatetrayne with two different nitriles to give unsymmetrically substituted bis(tetrahydroisoquinolines) was studied. The reaction proceeded with a range of alkyl and aryl nitriles with reasonable isolated yields.

BACKGROUND A novel method of fixation has been described for the treatment of pure depression fractures of the lateral tibial plateau. Fracture fragments are elevated through a reamed transtibial tunnel. An interference screw is then passed into the tunnel to buttress fracture fragments from beneath. This method of fixation has perceived benefits but there have been no studies to demonstrate th...

This highlight review summarizes our recent studies of macrocyclic receptors with precise molecular recognition properties based on two concepts, assembly metal complex units, and desymmetrization components. The metallomacrocycles realized a unique binding by utilizing multipoint coordination rigidity the units. desymmetrized homooligomeric macrocycles achieved employing unsymmetrically arrang...