using uv-vis spectrophotometic method, the formation constants for interaction of cd2+(aq) andco2+(aq) ions with l-alanine were experimentally studied at ph = 4.1 ± 0.01 (50mm of potassiumhydrogen phthalate buffer), ionic strength of 0.1m potassium nitrate and at 5 differenttemperatures 15,20, 25,30 and 35°c. the optical absorption spectra of mixtures containingconsidered cations and l-alanine ...

transition-metal-substituted  (tms)  polyoxometalates  of  the  general  formula  [siw9m3o39], (where m = first row transition metal), has been synthesized and supported on anatase by sol–gel method under oil-bath condition. the tetrabutylammonium (tba) salts of the keggin-type polyoxotungstates  [siw9m3o39],  (m = vii, crii, mnii,  feii coii  and niii),  proved  to  be  green, reusable,  and  ...

The one-third paradigm of PBE0 density functional, PBE0-1/3, has shown to be a successful method for various properties. In this paper, the applicability of PBE0-1/3 is put into broader perspective for transition metals chemistry. As a comparative study, the performance of PBE0 and PBE0-1/3 has been assessed for geometries and vibrational frequencies of some transition metal hydrides and transi...

Transition-metal-substituted  (TMS)  polyoxometalates  of  the  general  formula  [SiW9M3O39], (where M = first row transition metal), has been synthesized and supported on anatase by sol–gel method under oil-bath condition. The tetrabutylammonium (TBA) salts of the Keggin-type polyoxotungstates  [SiW9M3O39],  (M = VII, CrII, MnII,  FeII CoII  and NiII),  proved  to  be  green, reusable,  and  ...

background: combination of glycation and oxidation is associated with diabetes mellitus. the aim of this study was to clarify the effect of glycated proteins in presence of transition metal ions on production of reactive oxygen species (ros) in rat hepatocyte suspension.  methods: glycated albumin was prepared by incubation of bovine serum albumin with 100 mm glucose in 0.3 m phosphate buffer a...

the major reason for the prediction of thermodynamic properties of mercury lies in the fact that itsintermolecular interactions highly depend on temperature and density. internal pressure is a good criterion toinvestigate the density dependence of the interatomic interactions. because its physical base is a forcetending to close together the molecules that is intermolecular interactions, and as...