a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...

The binary A(8)B phase (prototype Pt(8)Ti) has been experimentally observed in 11 systems. A high-throughput search over all the binary transition intermetallics, however, reveals 59 occurrences of the A(8)B phase: Au(8)Zn(dagger), Cd(8)Sc(dagger), Cu(8)Ni(dagger), Cu(8)Zn(dagger), Hg(8)La, Ir(8)Os(dagger), Ir(8)Re, Ir(8)Ru(dagger), Ir(8)Tc, Ir(8)W(dagger), Nb(8)Os(dagger), Nb(8)Rh(dagger), Nb(...

Biomedical materials can improve the life quality of a number of people each year. The range of applications includes such as joint and limb replacements, artificial arteries and skin, contact lenses, and dentures. So far the accepted biomaterials include metals, ceramics and polymers. The metallic biomaterials mainly contain stainless steel, Co-Cr alloys, Titanium and Ti-6Al-4V. Recently, bulk...

Non-stoichiometric Zr-based alloys were prepared, and the corresponding electrochemical properties were characterized as hydride electrode alloys. The microstructure and chemical composition of non-stoichiometric Zr–Ti–Mn–V–Ni hydride electrode alloys were systematically investigated by x-ray Rietveld refinement, transmission electron microscopy (TEM), and energy dispersive spectroscopy under T...

A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...

The local magnetic properties of Ag12TM and Pd12TM clusters with Ih symmetry (TM = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Y, Zr, Nb, Mo, Tc, Ru, Rh, and Pd have been systematically studied with the density functional formalism, and the Kohn-Sham equation is solved self-consistently with the discrete variational method (DVM). A special attention is paid to the comparisons of local magnetism for impuriti...

Abstract High entropy shape memory alloys (HE-SMAs) show reversible martensitic phase transformations at elevated temperatures. HE-SMAs were derived from binary NiTi, to which the elements Cu, Pd, Zr and Hf are added. They represent ordered complex solid solutions. Their high temperature is of B2 type, where added occupy sites in Ni-(Cu, Pd) Ti-sub-lattices (Zr, Hf). In present study, advanced ...

In this study, 115 samples taken from the stream sediments were analyzed for concentrations of As, Co, Cr, Cu, Ni, Pb, W, Zn, Au, Ba, Fe, Mn, Sr, Ti, U, V and Zr. In order to outline mineralization-derived stream sediments, various mapping techniques including fuzzy factor score, geochemical halos and fractal model were used. Based on these models, concentrations of Co, Cr, Ni, Zn, Ba, Fe, Mn, ...

Geochemical investigations have permitted the refinement of the environmental interpretation of the f-Member of the Qum formation, Central Basin, Iran, which has been established through detailed microfacies (MF) analysis. The analysis revealed that the f-Member carbonates consist of eight distinct microfacies designated by the letters A through H. On the basis of petrographic characteristi...

Base\Noble (Angstrom) Pd Pt Rh Ag 3.989 4.012 3.923 Au 3.998 4.022 3.929 Cd 4.022 4.047 3.955 Co 3.875 3.899 3.794 Cr 3.915 3.927 3.807 Cu 3.881 3.907 3.804 Fe 3.898 3.925 3.812 Hg 4.044 4.073 3.979 Ir 3.923 3.953 3.849 Mn 3.930 3.940 3.817 Mo 3.953 3.982 3.868 Nb 3.979 4.008 3.901 Ni 3.868 3.889 3.789 Os 3.909 3.944 3.841 Pd 3.944 3.968 3.868 Pt 3.953 3.979 3.876 Re 3.936 3.955 3.850 Rh 3.922 ...