l:lle or&n and fate of thiocyanate ion in the body have been of interest for more than a century. It has been generally accepted that the ion does not readily permeate normal cell membranes; t.hc distribution of thiocyanate ion in the body is the basis of a method for determination of extracellular fluid volume (1). Despite its assumed extracellular localization, thiocyanate ion is physiologica...

polypyrrole (ppy/cl) and polyaniline (pani/cl) synthesized chemically onto sawdust (sd)was used for removal of thiocyanate (scn-) ions from aqueous solutions. the effect of someimportant parameters such as ph, initial concentration, sorbent dosage, and contact time onuptake of scn- was investigated. ppy/sd was found to be much more effective sorbent thanpani/sd for uptake scn- from aqueous solu...

a new sorbent composed of 3-aminopropyltriethoxy-silane-coated magnetic nanoparticles, functionalized with rhodium(iii) porphyrin complex was synthesized and characterized by elemental analysis, x-ray diffraction (xrd), transmission electron microscopy (tem), fourier transform infrared spectroscopy (ft-ir) and thermogravimetric analysis (tga). the effect of some co-existing anions present in aq...

In a previous report (1) we have shown that a small fraction of the sulfur of injected thiocyanate is converted to sulfate by the rat. The conversion of thiocyanate to sulfate had been predicted to occur as the result of the physiological activity of thiocyanate ion which is known to be a goitrogen and a hypotensive agent. Our results could not be taken as unequivocal evidence for the metabolis...

An accurate, inexpensive and less laborious liquid-liquid extractive spectrophotometric procedure for the determination of thiocyanate ions in aqueous media has been developed. The method has been based upon the formation of a yellow colored complex ion associate of the ion-pairing reagent 1-(3, 5-diamino-6-chloropyrazinecarboxyl) guanidine hydrochloride monohydrate, namely amiloride hydrochlor...

A procedure for the determination of iodide, thiocyanate and perchlorate ions in environmental water by two-dimensional ion chromatography has been developed. At first the iodide, thiocyanate and perchlorate ions were separated from interfering ions by a column (IonPac AS16, 250 mm x 4 mm). The iodide ion, thiocyanate and perchlorate ions were then enriched with an enrichment column (MAC-200, 8...

In a previous paper (1) we reported data, based upon the use of radiosulfur, showing that in the rat the affinity of the whole thyroid for thiocyanate ion is slight but is significantly greater than in other tissues. Baumann and Metzger (2), using different analytical procedures, reported a similar observation. The uptake of thiocyanate ion by the thyroid is of especial interest because of the ...

The Basin Hopping search method is used to find the global minima (GM) and map the energy landscapes of thiocyanate-water clusters, (SCN)(H2O)n with 3–50 water molecules, with empirical potentials describing the ion-water and water-water interactions. (It should be noted that beyond n = 23, the lowest energy structures were only found in 1 out of 8 searches so they are unlikely to be the true G...

1,4-bis(triphenylphosphonium)-2-butene dichloride was developed as a new phase transfer catalyst. This quaternized phosphonium salt catalyzed the regioselective ring opening of epoxides by thiocyanate ion to give β-hydroxy thiocyanates in high yields under mild conditions.

Thiocyanate ion is oxidized at acid pH by hydrogen peroxide to sulfate and cyanide. The reaction is catalyzed in the erythrocyte by hemoglobin acting as a peroxidase (donor: Hz02 oxidoreductase, EC 1.11.1.7). Kinetic studies show thiocyanate ion fulfdls criteria for a substrate for the peroxidase. The peroxidase activity is enhanced by haptoglobin and inhibited by azide, aminotriazole, fluoride...