Metals that work at high temperatures (for instance, superalloys in gas-turbines) depend on thermally grown oxide (TGO, commonly alumina) to withstand corrosion attack. Nickel Aluminide (NiAl) as one superior alumina TGO former plays an important role in protective coatings for turbine blades in gas-turbine engines used for aircraft propulsion and power generation. Lowering TGO growth rate is e...

Models that characterize the displacement instability of the thermally grown oxide (TGO) found in some thermal barrier systems are reviewed, consolidated and extended. It is demonstrated that the simulations are only consistent with the observations whenever the bond coat and TGO both undergo plastic deformation. The TGO yields at the peak temperature, during growth, while the bond coat yields ...

The microstructures of the thermally grown oxide (TGO) in as-coated electron beam physical vapor deposited (EB-PVD) thermal barrier coatings (TBCs) were examined by scanning transmission electron microscopy (STEM) as a function of demonstrated TBC lifetime in a thermally cycled environment. As-coated TBC specimens were selected for analysis based on individual statistical significance in overal...

The cyclic displacement instability exhibited by a thermally grown oxide (TGO) in a thermal barrier system has been simulated using a scheme that embodies large-scale thickening. The investigation has three main objectives. (i) A sensitivity study that probes the influence of the thermo-mechanical properties of the bond coat. It uses properties that closely resemble those relevant to actual bon...

Thermally insulating ceramic coatings also known as thermal barrier coatings (TBCs) have been essential technologies to improve the performance and efficiency of advanced gas turbines in service at extremely high temperatures. The damage mechanisms of air-plasma sprayed YSZ thermal barrier coatings (TBC) with various microstructures were studied by microscopic techniques after thermal cycling. ...

Local residual stress in thermally grown oxide (TGO) layers is the primary cause of failure thermal barrier coating (TBC) systems, especially TBCs prepared by air plasma spray (APS) with a highly irregular TGO. Herein, distribution and evolution TGO layer APS were investigated as function oxidation time. The was measured from cross-sectional micrographs converted to actual inside coatings befor...

Stress development is one of the significant factors leading to the failure of thermal barrier coating (TBC) systems. In this work, stress development in the two phase mixed zone named phase transition layer (PTL), which grows between the thermally grown oxide (TGO) and the bond coat (BC), is investigated by using two different homogenization models. A constitutive equation of the PTL based on ...

Micromechanical models are developed to explore the effect of embedded metal layers upon thermal cycling delamination failure of thermal barrier coatings (TBCs) driven by thickening of a thermally grown oxide (TGO). The effects of reductions in the steady-state (i.e. maximum) energy release rate (ERR) controlling debonding from large interface flaws and decreases in the thickening kinetics of T...

Multilayer thermal barrier coatings (TBCs) on superalloy substrates are comprised of an intermetallic bond coat, a thermally grown oxide (TGO) layer, and a porous zirconia top coat that provides thermal protection. The TGO attains a thickness of 1±10 lm prior to failure, while the bond coat and zirconia layer are each about 50±100 lm thick. The preferred method for manufacturing TBCs comprises ...