At this study, thallium (I) ion-imprinted polymer, as a novel sorbent for Tl (I) and comparison with Tl(III) ion-imprinted polymer has been synthesized. This sorbent for preconcentration and solid-phase extraction of Tl(I) ions from aqueous solutions, used. Through preparing the binary complex of Tl(I) ions with 5, 7-dichloroquinoline-8-ol (DCQ) the particles of thallium (I) Ion-Imprinted P...

The kinetics of carbamoylcholine-mediated cation transport across the membrane of vesicles containing acetylcholine receptor have been measured on the physiologically relevant time scale of a few milliseconds. The stopped-flow spectroscopic approach utilizes thallium(I) as the cation transported into sealed vesicles containing a water-soluble fluorophore. Upon entry of thallium(I), fluorescence...

Trace amounts of thallium(I) can be determined using adsorptive cathodic stripping voltammetry in the presence of Xylenol Orange (XO). The reduction current of the thallium(I)-XO complex ion was measured by square-wave cathodic stripping voltammetry. The peak potential was at -0.44 V vs. Ag/AgCl. The effect of various parameters (pH, ligand concentration, accumulation potential and collection t...

In this paper, magnetically multiwalled carbon nanotubes (MMWCNTs) nanocomposite modified by methyl-2-[2-(2-2-[2-(methoxycarbonyl) phenoxy] ethoxyethoxy) ethoxy] benzoate was applied for magnetic solid-phase extraction (MSPE) of thallium(I) ions. Fourier transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) spectrometry and vibrat...

The formation constants of the species formed in the systems H+ + cytidine 5-monophosphate (CMP)and H+ + cytidine 5-monophosphate + Tl (I) ion have been determined in aqueous solution in a widepH range of 1.5 to 10.5 at 25 °C and different ionic strengths ranging from 0.1 to 1.5 moldm-3NaClO4, NaNO3, and NaCl using potentiometric-spectrophotometric technique. The composition ofthe complexes was...

the formation constants of the species formed in the systems h+ + cytidine 5
-monophosphate (cmp)and h+ + cytidine 5
-monophosphate + tl (i) ion have been determined in aqueous solution in a wideph range of 1.5 to 10.5 at 25 °c and different ionic strengths ranging from 0.1 to 1.5 moldm-3naclo4, nano3, and nacl using potentiometric-spectrophotometric technique. the composition ofthe complexes w...

Objectives: The present study is focused on the determination of thallium (I) ions in homeopathic drugs. Methods: The determination was carried out using the Differential Pulse Anodic Stripping Voltammetry (DPASV) technique coupled with the flow-injection measuring system (FIA-DPASV). Results: The thallium content was analyzed in two commercial homeopathic preparations (Thallium aceticum 5CH an...

Many Organothallium Compounds have been used in medicine, industry and antibacterial activity. Optical properties are among the most fascinating and useful properties of many complexes and have been extensively studied using a variety of optical spectroscopic techniques. A basic understanding of the optical properties and related spectroscopic techniques is essential for characterization about ...