in suspension polymerization, particle size distribution of polymer is the outcome of dynamic equilibrium between the break up and coalescence phenomena. the rates of break up and coalescence and consequently polymerization stability depend on several parameters, the most important of which are type and concentration of stabilizer. in this study, the effects of type and concentration of stabili...

tricalcium phosphate as hydroxyapatite is used as a suspension stabilizer in styrene polymerization process. particle size of tcp plays an essential role in the particles’ size distribution and geometrical form of polystyrene products. as the particle size of tcp is reduced, there will be much better chance to engulf the styrene particles. the higher the number of tcp particles surrounding each...

suspension polymerization processes are significantly important in polymer bead formation. one of the important factors for bead size control in these processes is variation in surface tension. in this research, the prediction of optimum concentration of a surface active agent was investigated on the basis of the experimental surface tension diagrams. the experimental data show that the desired...

A population balance model for batch suspension polymerization of vinyl chloride is presented. Break up into two equal volumes of droplets, binary aggregation and random mass exchanges between the colliding droplets are assumed, while the kinetic data of vinyl chloride polymerization are taken from the literature. The model and the process are analyzed by simulation applying a novel Monte Carlo...

Many methods have been developed for characterizing the particle size distribution (PSD) in a suspension polymerization reactor, but are restricted to suspensions with low volume fractions of polymer or to determining the PSD only at the end of the batch. Laser backscattering can be used to measure the chord length distribution for slurries with high particle densities. Here, a combination of i...

II. Preparation of polyelectrolytic hydrogels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1. Monomers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2. Polymer synt...

A number of processes are available: condensation-, interfacial-, suspensionand emulsion-polymerization. Suspension and emulsion polymerization are the preferred methods for the commercial production of polymer microsphere carrier particles and reference/standard particles for calibration of scientific instruments. In general, emulsion polymerization produces a smaller particle size and a narro...