The reactivity and removal kinetics of arsenite treated with single and mixed mineral systems of kaolinite, montmorillonite and goethite injected with iron sulfide under sulfidicanoxic conditions has been investigated. Using empirical models derived from Freundlich isotherm model, injection of sulfidic-anoxic solution of iron sulfide onto the mixed mineral systems enhanced proton coefficient of...

in this study, effects of solid concentration, temperature, and initial fe2+ concentration on bioleaching of sulfide mineral (chalcopyrite) obtained from sarcheshmeh copper mine in the region of kerman located in the south of iran were investigated. a mesophilic iron oxidizing bacterium, acidithiobacillus ferrooxidans has been isolated from a typical chalcopyrite copper concentrate of the menti...

Underlying formation pathways of dimethylmercury ((CH3)2Hg) in the ocean are unknown. Early work proposed reactions of inorganic Hg (Hg(II)) with methyl cobalamin or of dissolved monomethylmercury (CH3Hg) with hydrogen sulfide as possible bacterial mediated or abiotic pathways. A significant fraction (up to 90%) of CH3Hg in natural waters is however adsorbed to reduced sulfur groups on mineral ...

The reaction between dissolved sulfide and synthetic iron (oxyhydr)oxide minerals was studied in artificial seawater and 0.1 M NaCl at pH 7.5 and 25°C. Electron transfer between surface-complexed sulfide and solid phase Fe(III) results in the oxidation of dissolved sulfide to elemental sulfur, and the subsequent dissolution of the surface-reduced Fe. Sulfide oxidation and Fe(II) dissolution kin...

Delineation of oxide and sulfide zones in mineral deposits, especially in gold deposits, is one of the most essential steps in an exploration project that has been traditionally carried out using the drilling results. Since in most mineral exploration projects there is a limited drilling dataset, application of geophysical data can reduce the error in delineation of the sulfide and oxide zones....

Iron(III) (oxyhydr)oxides can represent the dominant microbial electron acceptors under anoxic conditions in many aquatic environments, which makes understanding the mechanisms and processes regulating their dissolution and transformation particularly important. In a previous laboratory-based study, it has been shown that 0.05 mM thiosulfate can reduce 6 mM ferrihydrite indirectly via enzymatic...

Sedimentary iron sulfide minerals play a key role in maintaining the oxygenation of Earth’s atmosphere over geological timescales; they also record critical geochemical information that can be used to reconstruct paleo-environments. On modern Earth, sedimentary iron sulfide mineral formation takes places in low-temperature environments and requires the production of free sulfide by sulfate-redu...