isotactic poly (1-butene), ipbu-1, was synthesized by using a metallocene catalyst. the thermodynamic phase behavior of polymer–organic solvents systems is very important in every polymer application.  in this paper, the solid–liquid equilibrium of ipbu-1 with different organic solvents (1-heptyne, cyclo octane) was studied by a mathematical model. by considering the experiments temperature-mol...

Varnish and sludge formation are considered as one of the most common problems in lubrication and hydraulic systems. In order to simulate the condition of sludge formation, base stock lubricant (Group 1 API) has been selected and exposed to heat in a laboratory setup. Sludge formation process accelerated in the laboratory scale and solid liquid equilibrium data were extracted. Then solid-liquid...

In spite of the increasing levels greenhouse gases in atmosphere, and their impact on environment, demand for natural/biogas will increase significantly coming few decades. To cover this demand, global energy industry is continuously exploiting sour gas reserves located around world. Nonetheless, has to be sweetened before practical utilization natural or biogas. The cryogenic separation techno...

Three extraction methods were compared for their efficiency to analyze sitagliptin and simvastatin in rat plasma by LC-MS/MS, including (1) liquid-liquid extraction (LLE), (2) solid phase extraction (SPE) and (3) supported liquid extraction (SLE). Comparison of recoveries of analytes with different extraction methods revealed that SLE was the best extraction method. The detection was facilitate...

The solid–liquid equilibrium (SLE) behavior and liquid–liquid extraction (LLX) abilities of deep eutectic solvents (DESs) containing (a) thymol L-menthol, (b) trioctylphosphine oxide (TOPO) L-menthol were evaluated. distribution coefficients (KD) determined for the solutes relevant two biorefinery cases, including formic acid, levulinic furfural, acetic propionic butyric L-lactic acid. Overall,...

The UNIQUAC activity coefficient model is extended to predict solid-liquid equilibrium of isotactic crystalline poly (1-butene), iPBu-1, in different organic solvents. The UNIQUAC activity coefficient model used in this work is based on the concept of group contribution and consists of combinatorial, residual and free volume terms. To account for branching of atom groups in the monomer structur...

Aiming to contribute drug pre-formulation, new eutectic mixtures were developed. Thymol, coumarin, or quaternary ammonium chlorides as excipients, combined with the active pharmaceutical ingredients (APIs) acetylsalicylic acid, acetaminophen, ibuprofen, ketoprofen, lidocaine. Their solid-liquid equilibrium (SLE) binary phase diagrams measured study eventual separation between compounds, prevent...