The metal ions constituents in plants reliable for determination of their medicinal, nutritional and toxicity properties. A novel, simple and accurate spectrophotometric method was developed for the simultaneous determination of Ag+, Cu2+ and Ni2+ ions in different medicinal plants without prior separation steps. This method was based on the different kinetic characteristics between the reactio...

three antituberculosis medications are investigated in this work consist of rifampicin, isoniazid and pyrazinamide. the ultra violet (uv) spectra of these compounds are overlapped, thus use of suitable chemometric methods are helpful for simultaneous spectrophotometric determination of them. a generalized version of net analyte signal standard addition method (gnassam) was used for determinatio...

a partial least squares (pls) calibration model was developed for the simultaneous spectrophotometricdetermination of pb (ιι), cu (ιι) and ni (ιι) using xylenol orange as a chromogenic reagent. the parameterscontrolling behavior of the system were investigated and optimum conditions were selected. the calibrationgraphs were linear in the ranges of 0.0–9.091, 0.0–2.719 and 0.0–2.381 ppm for lead...

a simple, accurate and precise hptlc- densitometry method for the simultaneousdetermination of abacavir, lamivudine and zidovudine in pharmaceutical tablet has beendeveloped. separation of tablet components was performed on aluminum backed hptlc plates(silica gel 60 f254 20×20 cm with 0.2 mm thickness, camag, muttenz, switzerland ) usingmethanol : chloroform : acetonitrile (4 : 8 : 3 v/v). good...

in this study, incorporation of iron ion-doped natrolite nanozeolite, multi-wall carbon nanotubes into chitosan-coated glassy carbon electrode for the simultaneous determination of ascorbic acid, epinephrine, uric acid and tyrosine is studied. the results show that the combination of multi-wall carbon nanotubes and iron ion-doped natrolite zeolite causes a dramatic enhancement in the sensitivit...

a simple, sensitive and rapid method for determination of trace amounts of nitrite ion in real samples is reported. the reaction is initiated by adding known volumes of a nitrite ion solution of identified concentration to acidic solutions of thionine which causes decolorizaiton of reagent with time. the absorbance changes is then monitored spectrophotometrically at lmax = 602nm at 25 °c. calib...

A new selective reagent was used for simultaneous determination of mercury and palladium in real samples with their different kinetic spectrophotometric properties. The method is based on the difference in the rate of the oxidation reaction of the recently synthesized reagent, nitro benzoyl diphenylmethylen phosphorane (N-BDMP), with Hg2+ and Pd2+. The kinetic profiles were monitored and record...

in this paper, multivariate calibration methods of partial least squares (pls) and principle component regression (pcr) were investigated in simultaneously determination of hydrazine (hz) and acetylhydrazine (ahz). the aforementioned methods are based on formation of the silver nanoparticles (agnps) from the reaction of hz and ahz with ag+ ions as oxidizing agent in the presence of citrate ions...

a spectrophotometric method for selective complexation reaction and simultaneous determination of mycophenolate mofetil (mpm), and mycophenolic acid (mpa) using three multivariate chemometric methods, i.e. partial least squares regression, principal component regression and principal component artificial neural networks, is proposed. the method is based on the complexation reaction of mpm and m...