in order to gain a better understanding of the chemistry of methanl-to-hydro-carbon conversion, it is necessary to determine the nature of the primary reaction products. experiments carried out in this work on h-zsm-11, using a continuous flow reactor linked to an on-line gas chromatograph demonstrated that ethylene and methane are the primary reaction products. the results obtained using solid...

an efficient and green method for the synthesis of pyrano[3,2-c]chromene or pyrano[4,3-b]pyrone derivatives is described by using a three-component condensation process of malononitrile, aldehyde, and 4-hydroxycoumarine or 4-hydroxypyrone in [bmim]bf4-licl as an ionic liquid.

electrode potential of 2-(2,3-dihydroxy phenyl)-1,3-dithiane (dpd) was investigated by means of cyclic voltammetry (cv) at various potential scan rates. the calculated value was compared with the experimental value obtained by cyclic voltammetry (cv). all experiments were done in aqueous phosphate buffer solutions at different phs. the experimental redox potential of dpd was obtained to be 0.75...

F or a time, membrane proteins proved intractable to X-ray crystallography. There were difficulties of overexpression and purification, multiple choices of solubilizing detergent that could only be decided by trial and error, unwillingness to crystallize, and often, poor diffraction from resultant crystals. However, the tide now seems to be turning, and in PNAS, Oldham and Chen (1) present an X...

A mild and efficient one-pot three-component and environmentally benign approach for the synthesis of a wide range of hydantoin annulated derivatives has been described. A multi-component reaction between a carbonyl compounds (ketone or aldehyde), potassium cyanide and ammonium carbonate (as cyanating agent and amine source, respectively leads to the formation of hydantoins. The proposed optimi...

a mild and efficient one-pot three-component and environmentally benign approach for the synthesis of a wide range of hydantoin annulated derivatives has been described. a multi-component reaction between a carbonyl compounds (ketone or aldehyde), potassium cyanide and ammonium carbonate (as cyanating agent and amine source, respectively leads to the formation of hydantoins. the proposed optimi...

silica gel has been used for synthesis of biscoumarin derivatives starting from 4-hydroxycoumarin and aryl aldehydes. the reaction conditions are completely in agreement with green chemistry principles including sing water as media and a recyclable and safe catalyst. this method is also simple and inexpensive and leads to high yield of products in short reaction times.

epoxides undergo regioselective ring opening with various nucleophiles using catalytic amount of nano magnesium oxide and water as solvent under mild reaction conditions. the remarkable features of this method are improved yields, high regioselectivity, and green chemistry agreement.