نتایج جستجو برای: Pyrrole 2-carboxilic acid
تعداد نتایج: 3077423 فیلتر نتایج به سال:
ABSTRACT The main objective of this work is to investigate the adsorption of Pyrrole 2-carboxylic acid (PCA) from O, N and C sites on the surface of pristine and Ni doped B12N12 nano cage by using density functional theory (DFT). The results of adsorption energy indicate that the adsorption of PCA on the surface of B12N12 and NiB11N12 is exoth...
In the title compound, C(5)H(5)NO(2), the pyrrole ring and its carboxyl substituent are close to coplanar, with a dihedral angle of 11.7 (3)° between the planes. In the crystal structure, adjacent mol-ecules are linked by pairs of O-H⋯O hydrogen bonds to form inversion dimers. Additional N-H⋯O hydrogen bonds link these dimers into chains extending along the a axis.
One-step reactions between squaric acid and pyrroles, such as 3-ethyl-2,4-dimethyl-pyrrole 1,2,5-trimethylpyrrole, in water provide the corresponding pyrrol-2-yl- pyrrol-3-yl-containing semisquaraines high yields. These serve useful precursors for synthesis of various non-symmetric pyrrole-containing squaraine dyes.
Seven pyrrole alkaloids isolated from Agelas sponges were tested for interactions with the cellular calcium homeostasis. Brominated pyrrole alkaloids reduced voltage dependent calcium elevation in PC12 cells. Dibromosceptrin was the most potent alkaloid with a half maximal concentration of 2.8 microM followed by sceptrin (67.5 microM) and oroidin (75.8 microM). 4,5-Dibromopyrrole-2-carboxylic a...
Abstract By combining isoquinoline‐5‐carboxilic acid with Cu(II) ions under several different conditions, we were able to obtain novel metallorganic materials, among which two 2D coordination polymers, CP 1 and 2 also characterized by SC‐XRD. Ratio of solvents (EtOH : DMF) in the mixture employed during their synthesis has a marked effect selecting formation one species or other, basically diff...
Corroles and oxacorroles were synthesized by acid-catalyzed, 2+2 condensation. The condensation afforded different corroles bearing core-heteroatoms at the predesignated locations. Regioselective α-α’ linkage between pyrrole and furan or between pyrrole and pyrrole was achieved by keeping the linking carbon at different position of starting dipyrromethanes. The condensation was only fruitful wh...
The key aroma components and the lipolysis in a dry cured sausage 'Sobrassada of Mallorca from black pig' were studied. Sobrassada was characterized by a fatty acid profile with a high content of monounsaturated fatty acids and by the generation during the curing process of polyunsaturated free fatty acids that were oxidized to generate flavor compounds. Eighty-four different volatile compounds...
In the title compound, C(5)H(4)BrNO(2), the non-H atoms of the pyrrole ring and the Br atom are approximately coplanar, with an r.m.s. deviation from the best fit plane of 0.025 (6) Å;. The dihedral angle between the plane of the carb-oxy group and this plane is 14.1 (2)°. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules together, forming corrugated sheets parallel to the bc plane.
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