Abstract In this article, five kinds of soybean oil-based polyols (polyol-E, polyol-P, polyol-I, polyol-B, and polyol-M) were prepared by ring-opening the epoxy groups in epoxidized oil (ESO) with ethyl alcohol, 1-pentanol, isoamyl p -tert-butylphenol, 4-methoxyphenol presence tetrafluoroboric acid as catalyst. The SOPs characterized FTIR, 1 H NMR, GPC, viscosity, hydroxyl numbers. Compared ESO...

Upon rewetting, lichens lose polyols through leaching. We quantified leaching losses for 21 species under simulated rainfall. Polyol concentrations in these lichens range from 1.0 to 8.8%, with a mean of 2.8%. Leaching losses range up to about 7.5 mg (polyol)/g (lichen dry weight) in a typical rain event. The rate of polyol leaching declines exponentially, becoming negligible within 1 hour of c...

Transesterification of palm olein with glycerol can increase the functionality by introducing additional hydroxyl groups to the triglyceride structure, an advantage compared to using palm olein directly as feedstock for producing palm-based polyol. The objective of this study was to synthesize transesterified palm olein-based polyol via a three-step reaction: (1) transesterification of palm ole...

Pluronic F127 polyol, a block copolymer of propylene oxide and ethylene oxide, was studied as an alternative to agar in culture media for nematodes, bacteria, fungi, actinomycetes, and plant tissues or seedlings, At a polyol concentration of 20% w/v, the culture media, semi-solid at room temperature (22 C) but liquid at lower temperatures, had minimal effects on the test organisms. Most of the ...

ru/al2o3 catalysts were prepared by conventional incipient wetness impregnation as well as colloid deposition of rucl3 precursor via in situ reduction with ethylene glycol (polyol) method on alumina support. the samples were characterized by tem, xrd and tpr techniques. the catalytic performance tests were carried out in a fixed-bed micro-reactor under different operating conditions. ethylene g...

Polyene macrolide antibiotics are naturally occurring antifungal agents. Members of this class include amphotericin B, which has been used widely to treat systemic fungal infections. A general synthetic strategy has been devised to prepare polyol chains associated with the polyene macrolides. Cyanohydrin acetonide alkylations were used to assemble the carbon skeleton, and a simple modification ...

this paper is a report on the synthesis of the fe3o4@ag core-shell with high saturation magnetization of magnetite nanoparticles as the core, by using polyol route and silver shell by chemical reduction. x-ray diffraction (xrd) and fourier transform infrared spectroscopy analyses confirmed that the particles so produced were monophase. the magnetic properties of the product were investigated by...

good dispersion of nano-particles in polymer matrices is a crucial parameter in determining the final properties of polymer nanocomposites. in this work, the distributions of cloisite 30b, cloisite 10a and cloisite 93a in ptmeg, popular polyols in the polyurethane manufacturing, were investigated in the nano, micro and macro scales. this investigation was carried out using x-ray diffraction, rh...

Polyol-containing confectionery offers considerable advantages over traditional sucrose-based confectionery in terms of reduced energy content and reduced cariogenicity. However, over-consumption of polyol confectionery may lead to gastrointestinal symptoms in some individuals. Rather than consider this as a distinct disadvantage to the consumer, this article discusses how careful consideration...

The purification of functional proteins is a critical pre-requisite for many experimental assays. Immunoaffinity chromatography, one of the fastest and most efficient purification procedures available, is often limited by elution conditions that disrupt structure and destroy enzymatic activity. To address this limitation, we developed polyol-responsive antibody mimetics, termed nanoCLAMPs, base...