atom transfer radical polymerization (atrp) of styrene was carried out at 105°c and a monte carlo simulation was employed to model the system. the variations of monomer conversion, the initiator concentration, average molecular weight, and molecular weight distribution were evaluated as the reaction proceeded. according to the results obtained, for similar reaction time, monomer conversion is h...

In this research thin film heterogeneous cation exchange membrane was prepared by interfacial polymerization of polyacrylic acid-co-iron nickel oxide nanoparticle son PVC based substrate. Spectra analysis confirmed graft polymerization conclusively. The SEM images showed that polymerized layer covers the membranes by simple gel network entanglement. Results exhibited that membrane water content...

ethylene was polymerized in slurry phase over a ticl4/mg(oc2h5)2 catalyst activated by al(c2h5)3. it was shown experimentally that mass transfer resistance has no effect on polymerization kinetics. after estimation ofthe active site concentration by inhibition method with carbon monoxide, the effects of polymerization temperature, monomer and cocatalyst  oncentrations and hydrogen were investig...

Background and Aim: Minimizing the polymerization shrinkage of composite resins is a critical goals in composite restorations. Many factors affect polymerization shrinkage. This study aimed to evaluate the effect of composite resin shade on polymerization shrinkage. Materials and Methods: In this in vitro study, 14 composite discs measuring 1.5×8 mm were fabricated. The samples were prepared u...

polybutadiene nanoparticles were synthesized via batch emulsion polymerization of butadiene in the presence of potassium persulfate, disproportionate rosinate potassium cation and t-dodecyl mercaptane as initiator, emulsifier and chain transfer agent, respectively. polymerization reaction was performed at different temperatures (60, 70 and 80 °c). conversion was measured at the various time int...

as we know oxygen is one of the main inhibitors of polymerization of vinyl acetate. therefore, nitrogen is used in order to make sure of system's high purity. to maintain purity it is necessary to find out the rate of the oxygensolution in polymerization system under different conditions of polymerization. it is concluded that incoming nitrogen to the system would remove the oxygen from th...

Actin polymerization has been shown to be sufficient to propel curved objects, for example beads and vesicles coated with the Listeria monocytogenes protein ActA. Recent studies suggest that actin polymerization on flat surfaces can also provide the propulsive force to push them forward.

in suspension polymerization, particle size distribution of polymer is the outcome of dynamic equilibrium between the break up and coalescence phenomena. the rates of break up and coalescence and consequently polymerization stability depend on several parameters, the most important of which are type and concentration of stabilizer. in this study, the effects of type and concentration of stabili...