the difficult to handle and store zinc borohydride, zn(bh4)2, is stabilized by supporting it on polyvinylpyridine. this new mild, efficient, selective, and regenerable polymer supported borohydride reducing agent reduces a variety organic compounds such as, aldehydes, a-b-unsaturated carbonyl compounds, acid chlorides, epoxides, disulfides, as well as reductive acetylation of carbonyl compounds...

poly(p-n-chlorostyrenesulphonamide) synthesized via direct chlorination of poly[(p-styrene) sulphonamide], can be used for selective chlorination of aromatic compounds. aromatic rings of the anisole, p-xylene, ethylbenzene and toluene are chlorinated with good yields. the polymer can be recovery, rechlorinated and reused several times.

a convenient, one-pot method for the synthesis of diazonium salt has been developed by the sequential diazotization of aromatic amines with nano2, polymer- supported periodic acid (ppia) and 2-naphthole under solvent-free conditions at room temperature. by using this method, several types of aromatic amine, containing electron-withdrawing and electron-donating groups, were rapidly converted to ...

A convenient, one-pot method for the synthesis of diazonium salt has been developed by the sequential diazotization of aromatic amines with NaNO2, polymer- supported periodic acid (PPIA) and 2-naphthole under solvent-free conditions at room temperature. By using this method, several types of aromatic amine, containing electron-withdrawing and electron-donating groups, were rapidly converted to ...

A convenient, one-pot method for the synthesis of diazonium salt has been developed by the sequential diazotization of aromatic amines with NaNO2, polymer- supported periodic acid (PPIA) and 2-naphthole under solvent-free conditions at room temperature. By using this method, several types of aromatic amine, containing electron-withdrawing and electron-donating groups, were rapidly converted to ...

the polymer supported hypochlorite ion is a facile selective oxidizing agent for the oxidation of various alcohols to aldehydes and ketones. similarly is successfully oxidizes various hantzsch type 1,4- dihydropyridines to corresponding pyridines.

Soluble polymers have been used as supports for reagent/catalyst immobilization and synthesis. Two polymers are commonly used in this context, linear polystyrene and poly(ethylene glycol). The complementary solubility properties of these polymers allow access to a wide range of chemistries. Parallel and combinatorial libraries of small molecules have been prepared using these polymers, and reag...