Abstract As a monomer, the [N-(alanine)] para-styrene sulfonamide (ASS) was prepared, from the reaction of para-styrene sulfonyl chloride and (S)-(+)-alanine in the presence of KOH 1M as a base, and CH3Cl was used as solvent. The monomer confirmed using FT-IR and 1H-NMR spectroscopy. Polystyrene [N-(alanine) sulfonamide] (PASS) was also prepared from the polymerization of [N-(alanine)] pa...

* corresponding author, e-mail: [email protected] ; tel : (216) 74276400 ; fax : (216) 74274437 ABSTRACT: In this work, we have studied the effect of the halide nature in the coupling of styrene with halide benzene catalysed by palladium acetate or chloride. The activation by a catalyst of phase-transfer type Aliquat-336 improves the reactivity in N, N-dimethylformamide-water mixture. The...

n,n-dichloropolystyrene sulfonamide as a decontaminant was synthesized in 5 steps from styrene monomer. styrene was first polymerized. then, sulfonation reaction was performed by h2so4 (c) followed by chlorination with pocl3 obtain chlorosulfonated polystyrene. amidification reaction was then applied to get sulfonamide resin. sulfonamide resin was treated with sodium hypochloride to obtain n,n-...

N,N-dichloropolystyrene sulfonamide as a decontaminant was synthesized in 5 steps from styrene monomer. Styrene was first polymerized. Then, sulfonation reaction was performed by H2SO4 (c) followed by chlorination with POCl3 obtain chlorosulfonated polystyrene. Amidification reaction was then applied to get sulfonamide resin. Sulfonamide resin was treat...

N,N-dichloropolystyrene sulfonamide as a decontaminant was synthesized in 5 steps from styrene monomer. Styrene was first polymerized. Then, sulfonation reaction was performed by H2SO4 (c) followed by chlorination with POCl3 obtain chlorosulfonated polystyrene. Amidification reaction was then applied to get sulfonamide resin. Sulfonamide resin was treat...

Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd-diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.

a new dimeric orthopalladated complex was synthesized via reaction of 2,3-dimethoxy benzaldehyde oxime with palladium chloride and lithium chloride in methanol as solvent and sodium acetate as base at room temperature. the catalytic activity of this dimeric [pd{c6h2(-ch=noh)-(ome)2-2,3}(µ-cl)]2 complex as an efficient, air, and moisture tolerant catalyst was investigated in mizoroki–heck cross ...

exfoliated poly (chloromethyl styrene-co-styrene)-g-polyacrylonitryle/organo- modified montmorillonite [p(cmst-co-st)-g-pan/o-mmt] nanocomposite was synthesized through solution intercalation method by using atom transfer and nitroxide mediated radical polymerization. at first, poly (chloromethyl styrene-costyrene) copolymer was synthesized by nitroxide - mediated “living” free radical polyme...

A new dimeric orthopalladated complex was synthesized via reaction of 2,3-dimethoxy benzaldehyde oxime with palladium chloride and lithium chloride in methanol as solvent and sodium acetate as base at room temperature. The catalytic activity of this dimeric [Pd{C6H2(-CH=NOH)-(OMe)2-2,3}(µ-Cl)]2 complex as an efficient, air, and moisture tolerant catalyst was investigated in Mizoroki–Heck cross ...

A new dimeric orthopalladated complex was synthesized via reaction of 2,3-dimethoxy benzaldehyde oxime with palladium chloride and lithium chloride in methanol as solvent and sodium acetate as base at room temperature. The catalytic activity of this dimeric [Pd{C6H2(-CH=NOH)-(OMe)2-2,3}(µ-Cl)]2 complex as an efficient, air, and moisture tolerant catalyst was investigated in Mizoroki–Heck cross ...