An incipient advanced oxidation process, solar photocatalytic ozonation (SPO), is reviewed in this paper with the aim of clarifying the importance of this process as a more sustainable water technology to remove priority or emerging contaminants from water. The synergism between ozonation and photocatalytic oxidation is well known to increase the oxidation rate of water contaminants, but this h...

The degradation of pesticide Carbendazim was investigated by combination of TiO2-based photocatalysis and ozonation. A batch annular photoreactor has been used for carrying out the combined process and the influence of TiO2 concentration, ozone dose and pH were investigated. The results showed that the removal rate increased with increase in ozone dosage upto 0.48 g/h and decreased above 1g/L o...

Removal of nine pharmaceutical compounds--acetaminophen (AAF), antipyrine (ANT), caffeine (CAF), carbamazepine (CRB), diclofenac (DCF), hydrochlorothiazide (HCT), ketorolac (KET), metoprolol (MET) and sulfamethoxazole (SMX)-spiked in a primary sedimentation effluent of a municipal wastewater has been studied with sequential aerobic biological and ozone advanced oxidation systems. Combinations o...

The photocatalytic activity of Mn doped TiO2 for the ozonation of tetradifon pesticide in aqueous solution was studied. Various loadings of catalysts Mn/TiO2 (1%, 2.5% and 5%) was prepared and characterized by standard analytical techniques. Photocatalyzed ozonation with 2.5% Mn/TiO2 yielded 100% degradation and mineralization of tetradifon in 2.0 h under basic pH conditions. The extent of degr...

The research in this Thesis has been mainly performed at the research group Trataguas, from the Departamento de Ingeniería Química y Química Física of the Universidad de Extremadura. It is a part of an extensive research program on the elimination of emerging contaminants (ECs) in water through the application of advanced oxidation processes (AOPs), being developed by the Trataguas group and fi...

Diffuse pollution and the presence in waters of so-called emerging pollutants, among others, represent a major global environmental problem [...]

Photocatalytic ozonation by Al-supported TiO(2) films is successfully applied to the mineralization of 4-cumylphenol, a recalcitrant endocrine disrupting compound. A possible reaction mechanism implying the intermediate formation of bisphenols is proposed on the grounds of HPLC-MS and FTIR analyses.

In this study, the photocatalytic ozonation process using either UV lamps with a wavelength close to a solar wavelength (UVsolar) or natural solar light was established to study the effects of the major operating parameters on the removal of a toxic disinfection by-product (DBP), dichloroacetonitrile (DCAN), from drinking water. Based on the test results of a bench system, the UVsolar/TiO2/O3 p...

The experimental degradation of a water soluble dye, potassium indigo tetrasulfonate salt, has been studied using stand-alone ozonation and photocatalytic oxidation process. Progress of the dye oxidation was followed by UV-VIS spectrophotometric measurements at controlled operating conditions. The organic content of reaction samples was measured to verify the process efficiency in dye mineraliz...