Quinacridone chemistry has been developed which provides a source of new compounds that have potential application in organic photovoltaic (OPV) devices. Phosphoryl chloride is used for the conversion carbonyl groups N,N′-dialkylquinacridones, generating reactive intermediates enable selective condensation with either one or two nucleophilic molecules under mild conditions.

ortho-Lithiation of cyclic aryl sulfonamides in the presence of phosphoryl chloride provides a very simple entry to fused polycyclic sultams (benzothiazolines and naphthathiazolines).

Louisianin A (1) was treated with phosphoryl chloride (POC13) at 120~ 125°C3) to obtain chloro derivative (2) in 86% yield. 2 was reduced by Zn-AcOH at 50°C4) to afford 3 (52% yield) and 4 (35% yield). Furthermore, under the same condition, 3 was dechlorinated to give 4 in 48% yield. Moreover, 4 was oxidized in the treatment of CrO3-pyridine5) to obtain louisianin C (5) in 75% yield. Finally, 5...

Different types of natural, commercial and modified asbestos fibres were tested in a highly standardized manner by peritoneal injection into rats and mice in order to assess their carcinogenicity. Differences in mesotheliomatogenic effect were found between the various materials tested. Of particular interest is the finding that treatment of the fibres with phosphorus oxychloride and heating to...

The variable mechanism for substitution of P-stereogenic phosphoryl chloride with alkynyl metallic reagents, which depends on temperature, stoichiometry of starting materials, and the structure of the nucleophilic reagent, is assumed as either SN2-like or Berry pseudorotation of pentacoordinated phosphorus intermediates, affording inversion and retention products, respectively. The formation of...

Accepted on 26 th December 2016, Published online on 27 th January 2017 _____________________________________________________________________________ ABSTRACT During the present investigation, a new series of 3,6-disubstituted[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole derivatives (3) were synthesized by refluxing a mixture of 3-substituted-4-amino-5-mercapto-1,2,4triazoles with substituted anilin...

[reaction: see text] Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.