We present a coherent and unified group of general explanations for the various phase transitions, which may occur in the seven naturally occurring petroleum fluids with emphasis on their heavy organics. The seven petroleum fluids include, in the order of their fluidity, natural gas, near-critical gas-condensate, light crude, intermediate crude, heavy oil, tar sand and oil shale. At first the n...

A petroleum fluid can be di®ided into three types of species: asphaltenes, resins, and oils. Asphaltenes and resins are polar, while the rest of the so-called oils are either nonpolar or mildly polar. The interaction among these species strongly affect asphaltene precipitation from petroleum fluids. Different measuring methods for asphaltenes in a petroleum fluid gi®e similar results, but diffe...

Metalworking fluid emulsion formulations produced from vegetable oils may be less toxic and may reduce disposal costs when compared with fluids formulated with petroleum-based oils. Experiments were performed on experimental emulsions made with unmodified and modified soybean oils to measure rates of mist production by impaction, centrifugal force and evaporation/recondensation mechanisms. Resu...

Chemically modifying vegetable oils to produce an alternative to petroleum-based materials is one of the most important emerging industrial research areas today because of the adverse effects of petroleum products on the environment and the shortage of petroleum resources. Biolubricants, bioplasticizers, non-isocyanate polyurethanes, biofuel, coating materials, biocomposites, and other value-ad...

Equations of state should be tuned to reservoir conditions by PVT tests for phase behavior modeling. This tuning is achievable via an optimization method. In this work, simulated annealing algorithm is applied as a global optimization method to parameter optimization for PC-SAFT from the statistical associating fluid theory incorporating hard chain as reference fluid. The optimization parameter...

NMR well logging of petroleum reservoir require the measurement of the NMR response of water, oil, and gas in the pore space of rocks at elevated temperatures and pressures. The viscosity of the oil may range from less than 1 cp to greater than 10,000 cp. Also, the oil and gas are not a single component but rather a broad distribution of components. The log mean T1 and T2 relaxation time of dea...

During the Deepwater Horizon disaster, a substantial fraction of the 600,000-900,000 tons of released petroleum liquid and natural gas became entrapped below the sea surface, but the quantity entrapped and the sequestration mechanisms have remained unclear. We modeled the buoyant jet of petroleum liquid droplets, gas bubbles, and entrained seawater, using 279 simulated chemical components, for ...

In the petroleum industry, measurements of the density and viscosity of petroleum reservoir fluids are required to determine the value of the produced fluid and the production strategy. Measurements of the density and viscosity of petroleum fluids require a transducer that can operate at reservoir conditions, and results with an uncertainty of about ±1% in density and ±10% in viscosity are need...