The structure of uranopilite, [(UO2)6(SO4)O2(OH)6(H2O)6](H2O)8, space group P1̄, a 8.896(2), b 14.029(3), c 14.339(3) Å, 96.610(4), 98.472(4), 99.802(4)°, V 1726.1(4) Å3, Z = 2, has been solved and refined on the basis of F2 for all unique data collected with monochromatic MoK X-radiation and a CCD-based detector to an agreement factor (R1) of 7.0%, calculated using 3907 unique observed reflecti...