the 13c chemical shifts for a series of compounds which includes carboxylic acids, aldehydes, ethers, ketones and hydrocarbons were simulated by using the parametric techniques. the observed chemical shifts were related to numerically encoded structural parametes called descriptors. two new electronic descriptors were added to the previous descriptors. ploting of experimental versus calculated ...

1 VaR (Value at Risk) estimates are currently based on two main techniques, the variance-covariance approach or simulation. Statistical and computational problems affect the reliability of these techniques. We illustrate a new technique, filtered historical simulation, that is designed to remedy some of the shortcomings of the simulation approach. We compare the estimates it produces with tradi...

Spectral analysis considers the problem of determining (the art of recovering) the spectral content (i.e., the distribution of power over frequency) of a stationary time series from a finite set of measurements, by means of either nonparametric or parametric techniques. This paper introduces the spectral analysis problem, motivates the definition of power spectral density functions, and reviews...

One of the interesting topics on multimedia domain is concerned with empowering computer in order to speech production. Speech synthesis is granting human abilities to the computer for speech production. Data-based approach and process-based approach are the two main approaches on speech synthesis. Each approach has its varied challenges. Unit-selection speech synthesis and statistical parametr...

one of the interesting topics on multimedia domain is concerned with empowering computer in order to speech production. speech synthesis is granting human abilities to the computer for speech production. data-based approach and process-based approach are the two main approaches on speech synthesis. each approach has its varied challenges. unit-selection speech synthesis and statistical parametr...

Similarity scores represent the basis for identity inference in biometric verification systems. However, because of the so-called miss-matched conditions across enrollment and probe samples and identity-dependent factors these scores typically exhibit statistical variations that affect the verification performance of biometric systems. To mitigate these variations, scorenormalisation techniques...