The performance of several palladium precatalysts, namely, palladium(II) acetate, palladium(0) nanoparticles encapsulated into poly(amidoamine) (PAMAM) dendrimers (Pd DENs), and palladium(II)-PAMAM complexes, in the Stille reaction between trichloro(phenyl)stannane and iodoarenes in water is compared. The reactivity of Pd DENs is similar or inferior to that of palladium(II) acetate, although th...

nowadays, palladium compounds due to their especial characteristics used in different industries, mainly in electrical power sources and chemical productions as a catalyst. therefore, pd concentration is increasing in our around that can be contaminant our environment due its toxic effects. in this work, a simple, selective and rapid flow injection method of analysis (fia) has been developed fo...

PURPOSE As novel therapeutic agents relevant to colon cancer therapy are explored continuously, we tested 4 R2edda-type ligand precursors O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoic acid (L1.2HCl-L4.2HCl) and corresponding palladium(II) and platinum(II) complexes against the human colon cancer cell lines CaCo-2, SW480 and HCT116. METHODS The effects of the teste...

Nowadays, palladium compounds due to their especial characteristics used in different industries, mainly in electrical power sources and chemical productions as a catalyst. Therefore, Pd concentration is increasing in our around that can be contaminant our environment due its toxic effects. In this work, a simple, selective and rapid flow injection method of analysis (FIA) has been developed fo...

in the present study, we investigated the effect of a new anticancer pd(ii) complex, 1,10-phenanthroline-n-butyl dithiocarbamato pd(ii) nitrate, on the heme releasing from human hemoglobin (hb) as well as alterations in the structure and function of hb using different spectroscopic methods of uv-vis, fluorescence and circular dichroism (cd)at two temperatures of 25 and 37 °c. fluorescence data ...

Reaction of a [2]catenane with Pd(OAc)2 binds both macrocycles to the metal, locking them in position; treatment with PdCl2, however, results in coordination of only one ring, producing a half-turn in the relative orientation of the [2]catenane components in both solution and the solid state.

A simple and rapid liquid-liquid extraction of palladium has been studied involving ion-pairing of bromocomplexes of palladium(II) with hexadecylpyridinium bromide (HDPB) dissolved in chloroform. The stoichiometry and distribution of (HDP)2PdBr4 between the aqueous and organic phase was investigated by spectrophotometric mole ratio method. The extraction efficiency of palladium(II) by HDPB was ...

Recent years have seen the rapid development of a new field of palladium catalysis in organic synthesis. This chemistry takes place outside the usually encountered Pd(0)/Pd(II) cycles. It is characterized by the presence of strong oxidants, which prevent further palladium(II)-promoted reactions at a given point of the catalytic cycle by selective metal oxidation. The resulting higher-oxidation-...

The sonochemical synthesis of stable palladium nanoparticles has been achieved by ultrasonic irradiation of palladium(II) nitrate solution. The starting solutions were prepared by the addition of different concentrations of palladium(II) nitrate in ethylene glycol and poly(vinylpyrrolidone) (PVP). The resulting mixtures were irradiated with ultrasonic 50 kHz waves in a glass vessel for 180 min....