the hybrid molten/solid in2o3 - 30-48 wt.% bi2o3 oxide materials were studied with respect to their transport properties. the conductivities, oxygen ion transport numbers and oxygen permeation fluxes have been measured by using the four-probe dc, volumetric measurements of the faradaic efficiency and gas flow techniques, respectively. we show that the oxygen permeability of the hybrid molten/so...

The hybrid molten/solid In2O3 - 30-48 wt.% Bi2O3 oxide materials were studied with respect to their transport properties. The conductivities, oxygen ion transport numbers and oxygen permeation fluxes have been measured by using the four-probe DC, volumetric measurements of the faradaic efficiency and gas flow techniques, respectively. We show that the...

The transport properties of various anion and cation exchange membranes were studied in different electrolyte solutions using chronopotentiometry technique to get insight about the influence of the counter ion on the transport properties of the membranes. The investigated samples include heterogeneous ion exchange membranes varying in the functionality of fixed charged gro...

in present research work, homogeneous anion exchange membranes based on polysulfone (qapsfs) were prepared via chloromethylation, amination and alkalization. in amination step, trimethylamine and n,n,n',n'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. the chloromethylated polysulfone was characterized by 1hnmr spectroscopy and chloromethylation degr...

In present research work, anion exchange membranes based on quaternized polysulfone with ammonium cation moieties (QAPSF) were prepared by chloromethylation, amination and alkalization. The chloromethylated polysulfone were characterized by 1HNMR spectroscopy and functionalization degree was determined according to peak area integration. Ion transport properties (ionic conductivity, ion exchang...

In present research work, homogeneous anion exchange membranes based on polysulfone (QAPSFs) were prepared via chloromethylation, amination and alkalization. In amination step, trimethylamine and N,N,N',N'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. The chloromethylated polysulfone was characterized by 1HNMR spectroscopy and chloromethylation degr...

In this study, ion exchange nanocomposite membranes was prepared by addition of Mg(OH)2 nanoparticles to a blend containing sulfonated polyphenylene oxide and sulfonated polyvinylchloride via a simple casting method. Magnesium hydroxide nanoparticles were synthesized via a facile sono-chemical reaction and were selected as filler additive in fabrication of ion exchange nanocomposite membranes. ...

Nanocomposite cation exchange membranes (CEMs) were prepared by adding various amounts of functionalized silica-coated magnetite nanoparticles to the sulfonated polyethersulfone (sPES) polymeric matrix. The particles were synthesized first by the co-precipitation method (M0). Different surface modifications were then carried out on them by grafting three functional groups of mercaptopropyl, pro...

We demonstrate the use of a novel pulse (18)O-(16)O isotopic exchange technique for the rapid determination of the oxygen surface exchange rate of oxide ion conductors while simultaneously providing insight into the mechanism of the oxygen exchange reaction, which contributes to the efficient development of devices incorporating these solids, such as solid oxide fuel cells and oxygen transport ...