the oxidative coupling of methane (ocm) performance over na-w-mn/sio2 at elevated pressures has been simulated by adaptive neuro fuzzy inference system (anfis) using reaction data gathered in an isothermal fixed bed microreactor. in the designed neuro fuzzy models, three important parameters such as methane to oxygen ratio, gas hourly space velocity (ghsv), and reaction temperature were conside...

for more than three decades, oxidative coupling of methane (ocm) process has been comprehensively investigated as an attractive alternative for the commercially available ethylene production technologies such as ethane and naphtha cracking. developing a suitable catalyst and proper reactor feeding policy, reviewing and deploying the efficient methods in the separation and purification of the un...

oxidative coupling of methane has been studied over (mn+a+w)/sio2 catalysts in a continuous–flow microreactor, where a represents an alkali ion of li, na, k or cs having different weight percents. the main aim of this study is to find the role of alkali ions in interaction between mn and w species with sio2 to make a proper structure for catalyzing oxidative coupling of methane (ocm) reaction. ...

in this article, the effect of operating conditions, such as temperature, gas hourly space velocity (ghsv), ch4/o2 ratio and diluents gas (mol% n2) on ethylene production by oxidative coupling of methane (ocm) in a fixed bed reactor at atmospheric pressure was studied over mn/na2wo4/sio2 catalyst. based on the properties of neural networks, an artificial neural network was used for model develo...

the oxidative coupling of methane (ocm) over m-na-mn/sio2 catalysts (m=w, cr, nb and v) was investigated using a continuous-flow quartz reactor at 775°c, 1 atm and 100 cm3min-1 gas flow rates, and correlated with the observed structure and redox properties.the interaction effects of the metal-metal and metal-support on the methane conversion and c2+ yield were investigated using x-ray diffracti...

For more than three decades, Oxidative Coupling of Methane (OCM) process has been comprehensively investigated as an attractive alternative for the commercially available ethylene production technologies such as ethane and naphtha cracking. Developing a suitable catalyst and proper reactor feeding policy, reviewing and deploying the efficient methods in the separation and purification of the un...

Gas-phase methyl radicals have been long proposed as the key intermediate in catalytic oxidative coupling of methane, but the direct experimental evidence still lacks. Here, employing synchrotron VUV photoionization mass spectroscopy, we have directly observed the formation of gas-phase methyl radicals during oxidative coupling of methane catalyzed by Li/MgO catalysts. The concentration of gas-...

The oxidative coupling of methane (OCM) performance over Na-W-Mn/SiO2 at elevated pressures has been simulated by adaptive neuro fuzzy inference system (ANFIS) using reaction data gathered in an isothermal fixed bed microreactor. In the designed neuro fuzzy models, three important parameters such as methane to oxygen ratio, gas hourly space velocity (GHSV), and reaction temperature were conside...