نتایج جستجو برای: Octahedral complex

تعداد نتایج: 786895  

Journal: :iranian journal of mathematical chemistry 2016
s. fujita

stereoisograms of octahedral complexes are classified into five types (type i--typev) under the action of the corresponding rs-stereoisomeric group. their enumeration is accomplished in a type-itemized fashion, where fujita's proligand method developed originally for combinatorial enumeration under point groups (s. fujita, theor. chem. acc., 113, 73--79 (2005)) is extended to meet the requireme...

Journal: :inorganic chemistry research 0
soraia meghdadi isfahan university of technology kurt mereiter vienna university of technology, austria narges shams mohammadi isfahan university of technology ahmad amiri department of chemistry, university of tehran

an octahedral cobalt(iii) complex, trans-[(me2bpb)co(bzlan)2]clo4 (1), with h2me2bpb = n,n’-(4,5-dimethyl-1,2-phenylene)dipicolinamide and bzlan = benzylamine, has been synthesized and characterized by elemental analyses, ir, uv-vis, and 1h nmr spectroscopy. the structure of this complex has been determined by x-ray crystallography. the me2bpb2– is a di-anionic tetradentate ligand furnishing a ...

2001
Hiroshi SAKIYAMA

MagSaki software was developed for the magnetic analysis of dinuclear high-spin cobalt(II) complexes. This software performs magnetic analysis to determine magnetic parameters using several types of theoretical calculations, such as the following: (1) a mononuclear complex in an isotropic octahedral field, (2) a mononuclear complex in an axially distorted octahedral field, (3) a dinuclear compl...

Journal: :iranian journal of chemistry and chemical engineering (ijcce) 2014
hamid golchoubian omeleila nazari ghodsieh soleimani mojtaba mohseni

nickel(ii) complex of [nil2](clo4)2, where l is an unsymmetrical tridentate ligand of 2-(2-aminoethyl)imino-3-butanone oximehas been synthesized by a template condensation reaction. the complex was characterized on the basis of microanalytical, spectroscopic, and other physicochemical properties. x-ray diffraction study of the complex reveals nickel(ii) center in a distorted octahedral environm...

Journal: :Science 2006
John F Berry Eckhard Bill Eberhard Bothe Serena DeBeer George Bernd Mienert Frank Neese Karl Wieghardt

The hexavalent state, considered to be the highest oxidation level accessible for iron, has previously been found only in the tetrahedral ferrate dianion, FeO4(2-). We report the photochemical synthesis of another Fe(VI) compound, an octahedrally coordinated dication bearing a terminal nitrido ligand. Mössbauer and x-ray absorption spectra, supported by density functional theory, are consistent...

Journal: :inorganic chemistry research 2015
soraia meghdadi ahmad amiri kurt mereiter narges shams mohammadi

an octahedral cobalt(iii) complex, trans-[(me2bpb)co(bzlan)2]clo4 (1), with h2me2bpb = n,n’-(4,5-dimethyl-1,2-phenylene)dipicolinamide and bzlan = benzylamine, has been synthesized and characterized by elemental analyses, ir, uv-vis, and 1h nmr spectroscopy. the structure of this complex has been determined by x-ray crystallography. the me2bpb2– is a di-anionic tetradentate ligand furnishing a ...

An octahedral cobalt(III) complex, trans-[(Me2bpb)Co(bzlan)2]ClO4 (1), with H2Me2bpb = N,N’-(4,5-dimethyl-1,2-phenylene)dipicolinamide and bzlan = benzylamine, has been synthesized and characterized by elemental analyses, IR, UV-Vis, and 1H NMR spectroscopy. The structure of this complex has been determined by X-ray crystallography. The Me2bpb2– is a di-anionic tetradentate ligand furnishing a ...

Ghodsieh Soleimani Hamid Golchoubian, Mojtaba Mohseni Omeleila Nazari

Nickel(II) complex of [NiL2](ClO4)2, where L is an unsymmetrical tridentate ligand of 2-(2-aminoethyl)imino-3-butanone oximehas been synthesized by a template condensation reaction. The complex was characterized on the basis of microanalytical, spectroscopic, and other physicochemical properties. X-ray diffraction study of the complex revea...

Aliakbar Dehno Khalaji

In this paper, single crystalline octahedral Co3O4 with dimensions about 100–500 nm and smooth surface has been prepared by solid-state thermal decomposition of cobalt(II) Schiff base complex Co((3,4-MeO-ba)2 en)Cl2 as new precursor at 450ºC under air atmosphere for 3.5 h. Surface morphology of the products were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray powder ...

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