The chemical kinetics of n-heptane (n-C 7 H 16 ) – an important reference compound for real fuels – oxidation are well studied at stoichiometric and lean conditions. However, there is only limited information on the n-heptane chemical kinetics in fuel-rich combustion. In order to verify the accuracy of chemical kinetic models at these conditions, the oxidation of rich n-heptane mixtures has bee...

High-speed gas sampling experiments to measure the intermediate products formed during fuel decomposition remain challenging yet important experimental objectives. This article presents new speciation data on two important fuel reference compounds, n-heptane and n-butanol, at practical thermodynamic conditions of 700 K and 9 atm, for stoichiometric fuel-to-oxygen ratios and a dilution of 5.64 (...

0010-2180/$ see front matter 2011 The Combust doi:10.1016/j.combustflame.2011.08.015 ⇑ Corresponding author. Fax: +1 607 255 1222. E-mail address: [email protected] (C.T. Avedisian). The droplet burning characteristics of binary blends of iso-octane, n-heptane and toluene were studied in an ambience that minimizes external convection and promotes spherical droplet flames. The results are compare...

Autoignition of binary blends of n-butanol and n-heptane was studied in a rapid compression machine at an equivalence ratio of 0.4 and a compressed pressure of 20 bar with the compressed temperature varying from 700 K to 907 K. Within the temperature range covered in this study, no cool flame or negative temperature coefficient behavior was observed for neat n-butanol. With the presence of n-he...

The neurotoxicity of n-pentane, n-hexane, and n-heptane have been studied in Wistar strain male rats after exposure to 3000 ppm of n-pentane, n-hexane, or n-heptane for 12 hours a day for 16 weeks. The nerve conduction velocity and the distal latency were measured before the beginning of the exposure and after exposure for four, eight, 12, and 16 weeks. The experiment showed that n-hexane distu...

This paper focuses on the reaction zone and soot emission characteristics of swirl spray flames iso-pentanol blends. OH planar laser induced fluorescence (PLIF) measurements were used to study lift-off local extinction features. Soot was investigated using time-resolved two-colour incandescence (2C-LII) diagnostic technique. Fuels in this n-heptane, iso-pentanol, ethanol blends n-heptane/iso-pe...

A reduced primary reference fuel (PRF)-alcohol-di-tert-butyl peroxide (DTBP) mechanism with 108 species and 435 reactions, including sub-mechanisms of PRF, methanol, ethanol, DTBP, and the four butanol isomers, is proposed for homogeneous charge compression ignition (HCCI) engine combustion simulations of butanol isomers/nheptane mixtures. HCCI experiments fueled with butanol isomer/n-heptane m...