In this paper, an environmentally benign access to synthesize Bis(pyrazol-5-ol) derivatives was developed through the one pot pseudo five component condensation reaction of phenyl hydrazine with ethyl acetoacetate, and different aryl/heteroaryl aldehydes using morpholinium glycolate as the homogeneous reusable catalyst under solvent-free conditions at 80 °C. Further, the ionic liquid was prepar...

In this paper, an environmentally benign access to synthesize Bis(pyrazol-5-ol) derivatives was developed through the one pot pseudo five component condensation reaction of phenyl hydrazine with ethyl acetoacetate, and different aryl/heteroaryl aldehydes using morpholinium glycolate as the homogeneous reusable catalyst under solvent-free conditions at 80 °C. Further, the ionic liquid was prepar...

The asymmetric unit of the title compound, (C(4)H(10)NO)(2)[SbCl(5)], consists of two morpholinium cations in chair conformations, and a penta-chloridoanti-monate dianion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment. The morpholinium cations are connected to each other by N-H⋯O hydrogen bonds, and they link the chloride anions and the anti-monate SbCl(3...

The anhydrous salts morpholinium (tetra-hydro-2-H-1,4-oxazin-4-ium) phen-oxy-acetate, C4H10NO(+)·C8H7O3 (-), (I), morpholinium (4-fluoro-phen-oxy)acetate, C4H10NO(+)·C8H6 FO3 (-), (II), and isomeric morpholinium (3,5-di-chloro-phen-oxy)acetate (3,5-D), (III), and morpholinium (2,4-di-chloro-phen-oxy)acetic acid (2,4-D), C4H10NO(+)·C8H5Cl2O3 (-), (IV), have been determined and their hydrogen-bon...

In the title salt, C(4)H(10)NO(+)·ClO(4) (-), which has three independent formula units, the cations are linked into chains along [100] by N-H⋯O hydrogen bonds. Each cation acts both as a donor and as an acceptor, and every cation makes one N-H⋯O hydrogen bond with a ClO(4) (-) anion. The crystal studied was an inversion twin.

After a preliminary period in light, leaf disks floated on 10 mm alpha-hydroxy-2-pyridinemethanesulfonic acid to inhibit glycolate oxidase accumulate glycolate at average initial rates of 67 micromoles in tobacco and 8 micromoles per gram fresh weight per hour in maize under optimal conditions in air. In the presence of (14)CO(2), the glycolate synthesized has a high specific radioactivity in i...

A new organic-inorganic hybrid compound, penta-morpholinium hexa-hydrogen hexa-molybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[Fe(III)(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central Fe(III) ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites...