oxidation of ethylene to ethylene oxide over silver catalyst and selenium modified catalyst has been studied by continuous flow and pulse techniques over the temperature range of 230-280 °c. the results are discussed in terms of reaction mechanisms proposed by others, rejecting mechanisms which involve peroxide formation. it has been shown that not only selectivity towards ethylene oxide produc...

Oxidation of ethylene to ethylene oxide over silver catalyst and selenium modified catalyst has been studied by continuous flow and pulse techniques over the temperature range of 230-280 °C. The results are discussed in terms of reaction mechanisms proposed by others, rejecting mechanisms which involve peroxide formation. It has been shown that not only selectivity towards ethylene oxide pr...

Catalysts based on silver supported on foam ceramics and modified by Zr, Ce and La oxides have been studied in the process of partial oxidation of methanol to formaldehyde. The foam catalysts exhibit high catalytic, mechanical and gas -dynamic properties exceeding the characteristics of conventional crystalline and supported silver samples. Modifying additives of Zr and Ce oxides raise activity...

*Corresponding Author: [email protected] Abstract In this work, a new method was developed for the catalytic reduction of hydrogen peroxide at glassy carbon electrode modified with silver nanoparticles and multi-wall carbon nanotubes. Silver incorporated in this modified electrode acted as catalyst to reduce hydrogen peroxide. First, the electrochemical behavior of silver, incorporated in m...

Size separation of silver nanoparticles was investigated in counter-current chromatography (CCC) based on a unique step-gradient extraction process. Carboxylate anions were modified on silver nanoparticles to produce water-dispersible nanoparticles. The aqueous nanoparticles were readily transferred to the organic phase (toluene/hexane = 1:1, v/v) together with the phase transfer catalyst, tetr...

A low-cost, solution-processed, versatile, microfluidic approach is developed for patterning structures of highly conductive metals (e.g., copper, silver, and nickel) on chemically modified flexible polyethylene terephthalate thin films by in situ polymer-assisted electroless metal deposition. This method has significantly lowered the consumption of catalyst as well as the metal plating solution.

A four stage semi-pilot scale RFR reactor with ceramic disks as support for TiO2 modified 9 with silver particles was developed for the removal of organic pollutants. The design presented in 10 this article is an adaptation of the rotating biological reactors (RBR) and its coupling with the 11 modified catalyst provides additional advantages to designs where a catalyst in suspension is used. 12...

A four stage semi-pilot scale RFR reactor with ceramic disks as support for TiO₂ modified with silver particles was developed for the removal of organic pollutants. The design presented in this article is an adaptation of the rotating biological reactors (RBR) and its coupling with the modified catalyst provides additional advantages to designs where a catalyst in suspension is used. The optima...

A mild and rapid method for the iodination of arenes that utilizes silver(I) triflimide as a catalyst for activation of N-iodosuccinimide has been developed. The transformation was found to be general for a wide range of anisole, aniline, acetanilide, and phenol derivatives and allowed the late-stage iodination of biologically active compounds such as PIMBA, a SPECT imaging agent of breast canc...