Petroleum refineries utilize thermal cracking, catalytic cracking and hydrogenation processes to produce high quality oil products. Hydrodesulfurization is one of the most important methods to remove sulfur from petroleum fractions. Heavy oil contains various types of sulfur compound. The structure of the sulfur compounds affects the ease of sulfur removal1). Acyclic sulfur compounds including ...

Because of the requirement for low sulfur content of fuel oils, it is necessary to develop alternative methods for desulfurization of heavy fuel oil. Due to the disadvantages of HDS technologies such as costs, safety and green environment, new methods have been developed. Among these methods is ultrasoundassisted oxidative desulfurization. Using ultrasound-assisted oxidative desulfurization, co...

A particular type of mesopore extrudates gamma alumina was prepared; which is used as the catalyst in the heavy oil desulfurization unit. Extrudates gamma-alumina support has been made of the boehmite powder from Nephlinsinite mine ores (Surface Area (S.A.) >200 m2/g, Pore Volume (P.V.) =0.48 cm3/g, Average Pore Diameter (A.P.D.) = 8.10 nm); then, many samples of extru...

MCM-41 mesoporous silica is synthesized based on a self assembly method, using a quaternary ammonium template, CTAB for the adsorption of sulfur compounds from model oil (1.0 mmol/l DBT in dodecane solution). Then the adsorption capability of MCM-41 assembled on the surface of bacterium Rhodococcus erythropolis IGTS8 is examined regarding the improvement of the biodesulfurization process of...

The co-processing of an unconventional type of Jatropha bio-oil with petroleum distillates over mesoporous alumina-supported CoMo and NiMo sulfide catalysts (denoted CoMo/γ-Al2O3 and NiMo/γ-Al2O3) was studied. Either a stainless-steel high-pressure batch-type reactor or an up-flow fixed-bed reaction system was used under severe reaction conditions (330–350 ◦C and 5–7 MPa), similar to the condit...

A new rapid, very simple and one-step sol-gel strategy for the large-scale preparation of highly porous γ-Al₂O₃ is presented. The resulting mesoporous alumina materials feature high surface areas (400 m² g-1), large pore volumes (0.8 mL g-1) and the γ-Al₂O₃ phase is obtained at low temperature (500 °C). The main advantages and drawbacks of different preparations of mesoporous alumina materials ...

The growth of ordered nanorods of mesoporous SBA-15 inside a porous alumina membrane has been achieved for the first time by a simple sol-gel method. The obtained SBA-15 nanorods themselves have ordered hexagonal mesochannels with a size of about 6 nm and have been arranged to form hexagonal arrays by the limitation of pores of the alumina membrane. The synthesized alumina membrane with mesopor...

This paper presents a part of our work on understanding the effect of nanoscale pore space confinement on ion sorption by mesoporous materials. Acid-base titration experiments were performed on both mesoporous alumina and alumina particles under various ionic strengths. The point of zero charge (PZC) for mesoporous alumina was measured to be approximately 9.1, similar to that for nonmesoporous ...