The geometric and electronic structures of both neutral and negatively charged lead sulfide clusters, (PbS)(n)/(PbS)(n)(-) (n = 2-10) were investigated in a combined anion photoelectron spectroscopy and computational study. Photoelectron spectra provided vertical detachment energies (VDEs) for the cluster anions and estimates of electron affinities (EA) for their neutral cluster counterparts, r...

Metal sulfide dielectric thin films have been deposited using dynamic wet chemistry processing on silver coated hollow glass waveguides (HGWs). The sulfides used were cadmium sulfide (CdS) and lead sulfide (PbS); both films have excellent infrared transparency and high refractive index contrast. The thickness of these thin films can be tailored to minimize the attenuation of the HGW over specif...

Cadmium sulfide and lead sulfide semiconducting nanoparticle chains have been fabricated for the first time by exploiting a general property of proteins, amyloidogenicity. The diameter of the CdS and PbS nanowires was tuned in the range of ∼50 to ∼350 nm by changing the process parameters. The nanoparticle chains were characterized by field emission scanning electron microscopy, UV-visible spec...

colloidal quantum dots offer broad tuning of semiconductor band structure via the quantum size effect. in this paper, we present a detailed investigation on the influence of the thickness of colloidal lead sulfide (pbs) nanocrystals (active layer) to the photovoltaic performance of colloidal quantum dot solar cells. the pbs nanocrystals (qds) were synthesized in a non-coordinating solvent, 1-oc...

In this work, four-terminal (4T) tandem solar cells were fabricated by using a methylammonium lead iodide (MAPbI3) perovskite cell (PSC) as the front-cell and sulfide (PbS) colloidal quantum dot (CQDSC) back-cell.

In this work, a novel lead sulfide (PbS) hierarchical superstructure, denoted as octapodal dendrites with a cubic center, has been synthesized employing a simple single-source precursor route. Our experimental results demonstrate that the novel hierarchical superstructure was generated through the delicate balance between the kinetic growth and thermodynamic growth regimes. Moreover, the morpho...

Colloidal quantum dots offer broad tuning of semiconductor band structure via the quantum size effect. In this paper, we present a detailed investigation on the influence of the thickness of colloidal lead sulfide (PbS) nanocrystals (active layer) to the photovoltaic performance of colloidal quantum dot solar cells. The PbS nanocrystals (QDs) were synthesized in a non-coordinating solvent, 1-oc...

Present paper reports a theoretical study to investigate the compressional behavior of nano PbS(,,) under high pressure by using different equations state. The dependence these parameters for three PbS particles sizes (2.6nm, 5.4nm and 8.8nm), have been calculated B-M EOS, m L-J EOS S-K EOS. Obtained results are compared with available experimental data. This comparison reveals validity well-kn...