a theoretical study of the kinetic and mechanism of 3-aug-cope rearrangement in gas phase was performed usingdet methods at b3lyp levels of theory with 6-3114ig(d,p) bass set at 298.i5k. equilibrium moleculargeometries and harmonic vibrational frequencies of the reactant, transition state did product were calculated. then,rate constant and activation thermodynamics parameters were calculated an...

in this research, graphene oxide- gold nanoparticles (aunp/go) were easily fabricated by a redox reaction between go and chloroauric acid without using any additional reductant and then used to stabilize pickering emulsions. (aunp/go) was investigated by ft-ir spectroscopy. the changes of parameters such as contact time, ph, amoxicillin initial concentration and temperature were tested and inve...

In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...

In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...

The effect of frying pressure on the kinetics of color changes during atmospheric and vacuum deep fat frying of Reshteh Khoshkar has been studied. The Hunter color parameters redness, yellowness, lightness and total color difference were used to estimate color changes during frying as a function of process. Lightness (L*) decreased from 85.37 to 75.01 with vacuum frying time, while redness (a*)...

OBJECTIVE This article seeks to test the hypothesis that repeated 1mg intravenous epinephrine dosing intervals of 3-minutes and 5-minutes results in differences in the total drug exposure and the maximum epinephrine concentration using simulated cardiopulmonary resuscitation (CPR) dosing. METHODS Published population pharmacokinetic parameters were identified in the literature and pharmacokin...

risk-based assessment methods are commonly used at the contaminated sites by hydrocarbon pollutants. this paper presents the results of a two-dimensional finite volume model of reactive transport of biodegradable btex which have been developed for the saturated zone of an unconfined aquifer in the pump station area of tehran oil refinery, iran. the model governing equations were numerically sol...

a biofilm sequencing batch reactor with a volume of 1.42 m3, nylon nets providing a 4,140 m2/m3 support area for biofilms and an automated operation with 8 hour cycles was studied. the duration of the experiment was 135 days. removal efficiencies e≥ 80% were obtained for carbonaceous matter, producing an effluent with 31±26.8 mg/l of filtered cod, 7±3.6 mg/l of bod5 and 12±3.2 mg/l of toc. the ...

in this paper, experimental data on the drying kinetics of corn in a packed and fluidized bed are presented. experimental research was conducted on a laboratory apparatus. corn was used as a material because of its significance in agriculture and the food industry. an analysis of the influence of the operational parameters (the drying medium velocity i. e. the fluidization number, the drying me...

Isothermal melt crystallization kinetics of PVDF was investigated by differential scanning calorimetry. Thin PVDF film has been fabricated by the solvent casting technique using dimethylformamide (DMF). Then, the samples were melted and subsequently crystallized in the range of the crystallization temperature (Tc) between 138 and 145 °C. The crystallization kinetics was derived from Avrami equa...