The article describes the studies of the iron speciation (the occurrence of Fe(II), Fe(III), and complexed iron) in acid leachable fraction of deposits. The speciation of iron was diverse for deposits of different origins and was the specific "fingerprint"-marker of deposition processes. The higher occurrence of Fe(II) may be connected with decantation which has been observed for lake sediments...

a simple, rapid and sensitive solvent assisted-dispersive solid phase extraction method was developed for the extraction of iron(ii) prior to its spectrophotometric determination. the fe(ii) reacted with 2,4,6-tris(2-pyridyl)-1,3,5-triazine, neutralized with sodium dodecyl sulfate and extracted onto the fine particles of benzophenone which were formed upon rapid injection of a mixture of benzop...

Citation: Buck KN, Gerringa LJA and Rijkenberg MJA (2016) An Intercomparison of Dissolved Iron Speciation at the Bermuda Atlantic Time-series Study (BATS) Site: Results from GEOTRACES Crossover Station A. Front. Mar. Sci. 3:262. doi: 10.3389/fmars.2016.00262 An Intercomparison of Dissolved Iron Speciation at the Bermuda Atlantic Time-series Study (BATS) Site: Results from GEOTRACES Crossover St...

The objective of this study is to develop a simple, environmentally benign alternate analytical method for simultaneous estimation of iron oxidation states. This proposed method of iron speciation is based on 1,10-phenanthroline (phen) modified redox potential of transition metal ions. In a pre-step excess cerium(IV) oxidizes iron(II) in sample to iron(III). Initial back titration of un-reacted...

Soluble iron in fine atmospheric particles has been identified as a public health concern by participating in reactions that generate reactive oxygen species (ROS). The mineralogy and oxidation state (speciation) of iron have been shown to influence fractional iron solubility (soluble iron/total iron). In this study, iron speciation was determined in single particles at urban and rural sites in...

A number of reports have appeared in literature calling attention to the depletion of essential metal ions during chelation therapy on β-thalassaemia patients. We present a speciation study to determine how the iron chelators used in therapy interfere with the homeostatic equilibria of essential metal ions. This work includes a thorough analysis of the pharmacokinetic properties of the chelatin...

Marine microorganisms are presented with unique challenges to obtain essential metal ions required to survive and thrive in the ocean. The production of organic ligands to complex transition metal ions is one strategy to both facilitate uptake of specific metals, such as iron, and to mitigate the potential toxic effects of other metal ions, such as copper. A number of important trace metal ions...

The synthesis and analytical applications of the new heterocyclic ligand are described. The complexation reaction of the ligand with some cations was studied in aqueous methanol at room temperature using the spectrophotometric method. Results revealed that only the absorption spectra of the Fe (III)–ligand complex show a high redshift of the absorption maximum in the aqueous methanol soluti...

Background, aim and scope In water systems, water quality and geochemical properties of sediments determine the speciation of trace metals, metal transport, and sediment-water exchange, influencing metal availability and its potential effects to biota. Studies from temperate climates have shown that iron-ore mining and tailing wastewaters, besides being a source of trace metals, usually show hi...

Iron is an essential element for almost all living species. Its environmental impacts on physiology and ecology of aquatic organisms are always the focus of limnology and oceanography. To gain insight into iron biogeochemistry and its environmental impacts in freshwater lakes, we collected and reviewed numerous studies on iron in combination with our own work. Our review reports iron sources, i...