fischer-tropsch catalysts with high activity and selectivity for olefins were produced using mordenite type sio2/al2o3= 12, 20, 28, 62 zeolite supported iron carbonyl compounds and were characterized by x-ray powder diffraction. the adsorptionof volatile fe(co)5 on the support surface was carried out under vacuum at room temperature. reduction les were monitored by vibrating sample magnetometer...

This paper presents the synthesis and characterization of monometallic and bimetallic cobalt and iron nanoparticles supported on alumina. The catalysts were prepared by a wet impregnation method. Samples were characterized using temperature-programmed reduction (TPR), temperature-programmed oxidation (TPO), CO-chemisorption, transmission electron microscopy (TEM), field emission scanning electr...

The adsorption properties of CO and H2 on iron-based catalyst with addition of Zr and Ni were investigated using temperature programmed desorption process. It was found that on the carburized iron-based catalysts, molecular state and dissociative state CO existed together. The addition of Zr was preferential for the molecular state adsorption of CO on iron-based catalyst and the presence of Ni ...

The widespread use of fuel cells is currently limited by the lack of efficient and cost-effective catalysts for the oxygen reduction reaction. Iron-based non-precious metal catalysts exhibit promising activity and stability, as an alternative to state-of-the-art platinum catalysts. However, the identity of the active species in non-precious metal catalysts remains elusive, impeding the developm...

The catalysts of iron-doped Mn-Ce/TiO2 (Fe-Mn-Ce/TiO2) prepared by sol-gel method were investigated for low temperature selective catalytic reduction (SCR) of NO with NH3. It was found that the NO conversion over Fe-Mn-Ce/TiO2 was obviously improved after iron doping compared with that over Mn-Ce/TiO2. Fe-Mn-Ce/TiO2 with the molar ratio of Fe/Ti = 0.1 exhibited the highest activity. The results...

The characteristics and performances of catalyst are the key in catalytic ultrasonic treatment of wastewater, and iron based catalysts are known for low cost, high accessibility and safety. This paper reviewed the current research status of iron-based catalysts in water treatment assisted by ultrasound. Zero valent iron, Fe3O4 and iron composited with other metals were analyzed, their behaviors...

Introduction The preparation and characterization of nanophase materials has received considerable attention in recent years, given their potential for improved performance as catalysts, high-strength materials, and semiconductor devices. For example, a recent breakthrough by Sun et al. (1) in the synthesis of highly-dispersed, silica-supported iron-platinum (FePt) bimetallic nanoclusters of co...

The Fischer-Tropsch Synthesis converts synthesis gas from alternative carbon resources, including natural gas, coal, and biomass, to hydrocarbons used as fuels or chemicals. In particular, iron-based catalysts at elevated temperatures favor the selective production of C2-C4 olefins, which are important building blocks for the chemical industry. Bulk iron catalysts (with promoters) were conventi...

N-doped graphene used as an efficient electron donor of iron catalysts for CO hydrogenation can achieve a high selectivity of around 50% for light olefins, significantly superior to the selectivity of iron catalysts on conventional carbon materials, e.g. carbon black with a selectivity of around 30% at the same reaction conditions.

Colloidal synthesis routes have been recently used to fabricate heterogeneous catalysts with more controllable and homogeneous properties. Herein a method was developed to modify the surface composition of colloidal nanocrystal catalysts and to purposely introduce specific atoms via ligands and change the catalyst reactivity. Organic ligands adsorbed on the surface of iron oxide catalysts were ...