نتایج جستجو برای: Intramolecular cyclizationyclization
تعداد نتایج: 13309 فیلتر نتایج به سال:
As the basis and preliminary work of future experimental study on PAHs formation under high temperature, theoretical computations on the intramolecular rearrangement reactions of sylvestrene (1-methyl-3-vinylcyclohexene) and 1,4-dimethyl-4-vinylcyclohexene are conducted and reveal that they may be transformed to themselves. The conversion between Dipentene and 2,4-dimethyl-4-vinylcyclohexen...
Allyl N-tosyloxycarbamates are found to be catalytically transformed into β-brominated oxazolidinones with FeBr(2)/n-Bu(4)NBr in t-BuOH.
the nmr spectra of azo dyes, 5-arylazobarbituric (5a-g), 5-arylazo-1,3-dimethylbarbituric(6a-g) and 5-arylazothiobarbituric acids (7a-g) were studied in dmso-d6 in differentconcentrations. an intramolecular hydrogen bond was observed and indicating that thehydrazone forms is mostly predominant. the peak of the hydrazone proton was severelybroadened and its chemical shift appeared at down field ...
In the present work, an extensive theoretical calculation study on Histidine-Histidine dipeptide in gas phase is done by using DFT method with Gaussian 98 program. Through investigations on the molecular geometries of this molecule it is found that there is six rings in the molecules not two rings. The presence of four intramolecular hydrogen bonds is responsible for the formation of additional...
Molecular structure, isomerism, conformational stability and intramolecular hydrogen bonding (IHB) of cis-enol forms of 1-(n-pyridyl)butane-1,3-diones (nPBD) (n = 2, 3, or 4) have been investigated by means of density functional theory (DFT) calculations. Energy differences for all possible nPBD cis-enol forms of isomers with respect to the most stable form of the correspondin...
in the present work, an extensive theoretical calculation study on histidine-histidine dipeptide in gas phase is done by using dft method with gaussian 98 program. through investigations on the molecular geometries of this molecule it is found that there is six rings in the molecules not two rings. the presence of four intramolecular hydrogen bonds is responsible for the formation of additional...
The NMR spectra of azo dyes, 5-arylazobarbituric (5a-g), 5-arylazo-1,3-dimethylbarbituric(6a-g) and 5-arylazothiobarbituric acids (7a-g) were studied in DMSO-d6 in differentconcentrations. An intramolecular hydrogen bond was observed and indicating that thehydrazone forms is mostly predominant. The peak of the hydrazone proton was severelybroadened and its chemical shift appeared at down field ...
an intramolecular palladium catalysed carbometalation followed by anion capture achieves construction of a model comprised of the a ring of vitamin d oxygen analogues.
An intramolecular palladium catalysed carbometalation followed by anion capture achieves construction of a model comprised of the A ring of Vitamin D oxygen analogues.
Protonation of the reactive intermediates generated in the raction between dalkyl acetylenedicarboxylates and triphenylphosphine by isonitrosoacetophenone leads to vinyltriphenylphosphonium salts, which undergo intramolecular Wittig reaction to produce dalkyl 4-phenyl-N-hydroxypyrrole-2,3-dicarboxylates in moderate yields.
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